dhr. prof. dr. B. (Bas) de Bruin

Lijst

Faculteit der Natuurwetenschappen, Wiskunde en Informatica
HIMS
POSTBUS 94720
1090 GS Amsterdam
Kamernummer: E1.48
B.deBruin@uva.nl
T: 0205256495

Publicaties
Nevenwerkzaamheden

refereed(108)
wetenschappelijk(2)
vakpublicatie(4)
populair wetenschappelijk(1)

2015

C. Rebreyend & B. de Bruin (2015). Photolytic N2 Splitting: A Road to Sustainable NH3 Production? Angewandte Chemie, International Edition, 54 (1), 42-44. doi: 10.1002/anie.201409727
S.H.A.M. Leenders, R. Gramage-Doria, B. de Bruin & J.N.H. Reek (2015). Transition metal catalysis in confined spaces. Chemical Society reviews, 44 (2), 433-448. doi: 10.1039/c4cs00192c[go to publisher's site]
S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt & J.N.H. Reek (2015). Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand. Chemical Science, 6 (2), 1027-1034. doi: 10.1039/C4SC02555E[go to publisher's site]
D.L.J. Broere, L.L. Metz, B. de Bruin, J.N.H. Reek, M.A. Siegler & J.I. van der Vlugt (2015). Redox-Active Ligand-Induced Homolytic Bond Activation. Angewandte Chemie, International Edition, 54 (5), 1516-1520. doi: 10.1002/anie.201410048
Y. Gümrükçü, B. de Bruin & J.N.H. Reek (2015). A Mechanistic Study of Direct Activation of Allylic Alcohols in Palladium Catalyzed Amination Reactions. CATALYSTS, 5 (1), 349-365. doi: 10.3390/catal5010349
A.M. Geer, A.L. Serrano, B. de Bruin, M.A. Ciriano & C. Tejel (2015). Terminal Phosphanido Rhodium Complexes Mediating Catalytic P - P and P - C Bond Formation. Angewandte Chemie, International Edition, 54 (2), 472-475. doi: 10.1002/anie.201407707
D.L.J. Broere, L.L. Metz, B. de Bruin, J.N.H. Reek, M.A. Siegler & J.I. van der Vlugt (2015). Redox-Active Ligand-Induced Homolytic Bond Activation. Angewandte Chemie, International Edition, 54 (5), 1516-1520. doi: 10.1002/anie.201410048
A.M. Geer, A.L. Serrano, B. de Bruin, M.A. Ciriano & C. Tejel (2015). Terminal Phosphanido Rhodium Complexes Mediating Catalytic P-P and P-C Bond Formation. Angewandte Chemie, International Edition, 54 (2), 472-475. doi: 10.1002/anie.201407707
S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt & J.N.H. Reek (2015). Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand. Chemical Science, 6 (2), 1027-1034. doi: 10.1039/c4sc02555e
R.M. Drost, D.L.J. Broere, J. Hoogenboom, S.N. de Baan, M. Lutz, B. de Bruin & C.J. Elsevier (2015). Allylpalladium(II) Histidylidene Complexes and Their Application in Z-Selective Transfer Semihydrogenation of Alkynes. European Journal of Inorganic Chemistry, 982-996. doi: 10.1002/ejic.201403104
P. Li, R. Zaffaroni, B. de Bruin & J.N.H. Reek (2015). New Tetracobalt Cluster Compounds for Electrocatalytic Proton Reduction: Syntheses, Structures, and Reactivity. Chemistry - A European Journal, 21 (10), 4027-4038. doi: 10.1002/chem.201405052

2014

A.J.C. Walters, J.H.N. Reek & B. de Bruin (2014). Computed Propagation and Termination Steps in [(Cycloocta-2,6-dien-1-yl)Rh-III(polymeryl)]+ Catalyzed Carbene Polymerization Reactions. ACS Catalysis, 4 (5), 1376-1389. doi: 10.1021/cs500160c
M. Otte, P.F. Kuijpers, O. Troeppner, I. Ivanović-Burmazović, J.N.H. Reek & B. de Bruin (2014). Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions. Chemistry - A European Journal, 20 (17), 4880-4884. doi: 10.1002/chem.201400055
S.R. Domingos, A. Huerta-Viga, L. Baij, S. Amirjalayer, D.A.E. Dunnebier, A.J.C. Walters, M. Finger, L.A. Nafie, B. de Bruin, W.J. Buma & S. Woutersen (2014). Amplified Vibrational Circular Dichroism as a Probe of Local Biomolecular Structure. Journal of the American Chemical Society, 136 (9), 3530-3535. doi: 10.1021/ja411405s
Y. Gumrukcu, B. de Bruin & J.H.N. Reek (2014). Hydrogen- Bond- Assisted Activation of Allylic Alcohols for Palladium- Catalyzed Coupling Reactions. ChemSusChem, 7 (3), 890-896. doi: 10.1002/cssc.201300723
H. Fang, Z. Ling, K. Lang, P.J. Brothers, B. de Bruin & X. Fu (2014). Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations. Chemical Science, 5 (3), 916-921. doi: 10.1039/c3sc52326h[go to publisher's site]
N.D. Paul, S. Mandal, M. Otte, X. Cui, X.P. Zhang & B. de Bruin (2014). Metalloradical Approach to 2H-Chromenes. Journal of the American Chemical Society, 136 (3), 1090-1096. doi: 10.1021/ja4111336
S. Pelties, D. Herrmann, B. de Bruin, F. Hartl & R. Wolf (2014). Selective P-4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides. Chemical Communications, 50 (53), 7014-7016. doi: 10.1039/c4cc02601b[go to publisher's site]
Y. Gumrukcu, B. de Bruin & J.N.H. Reek (2014). Dehydrative Cross-Coupling Reactions of Allylic Alcohols with Olefins. Chemistry - A European Journal, 20 (35), 10905-10909. doi: 10.1002/chem.201404026
D.L.J. Broere, B. de Bruin, J.N.H. Reek, M. Lutz, S. Dechert & J.I. van der Vlugt (2014). Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex. Journal of the American Chemical Society, 136 (33), 11574-11577. doi: 10.1021/ja502164f
Y. Gloaguen, C. Rebreyend, M. Lutz, P. Kumar, M. Huber, J.I. van der Vlugt, S. Schneider & B. de Bruin (2014). An Isolated Nitridyl Radical-Bridged {Rh(N-center dot)Rh} Complex. Angewandte Chemie, International Edition, 53 (26), 6814-6818. doi: 10.1002/anie.201403445
S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt & J.N.H. Reek (2014). Well-Defined BisMETAMORPhos PdI-PdI Complex: Synthesis, Structural Characterization, and Reactivity. Organometallics, 33 (24), 7293-7298. doi: 10.1021/om5010622
R.M. Drost, T. Bouwens, N.P. van Leest, B. de Bruin & C.J. Elsevier (2014). Convenient Transfer Semihydrogenation Methodology for Alkynes Using a PdII-NHC Precatalyst. ACS Catalysis, 4 (5), 1349-1357. doi: 10.1021/cs4011502
P. Li, S. Amirjalayer, F. Hartl, M. Lutz, B. de Bruin, R. Becker, S. Woutersen & J.N.H. Reek (2014). Direct Probing of Photoinduced Electron Transfer in a Self-Assembled Biomimetic [2Fe2S]-Hydrogenase Complex Using Ultrafast Vibrational Spectroscopy. Inorganic Chemistry, 53 (10), 5373-5383. doi: 10.1021/ic500777d
P. Dydio, R.J. Detz, B. de Bruin & J.H.N. Reek (2014). Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular Catalysis. Journal of the American Chemical Society, 136 (23), 8418-8429. doi: 10.1021/ja503033q
E. Jansen, M. Lutz, B. de Bruin & C.J. Elsevier (2014). Charge-Delocalized κC-2,N-NHC-Amine Complexes of Rhodium, Iridium, and Ruthenium. Organometallics, 33 (11), 2853-2861. doi: 10.1021/om5003599

2013

M.R. Panman, J. Vos, V. Bocokić, R. Bellini, B. de Bruin, J.H.N. Reek & S. Woutersen (2013). Exchanging Conformations of a Hydroformylation Catalyst Structurally Characterized Using Two-Dimensional Vibrational Spectroscopy. Inorganic Chemistry, 52 (24), 14294-14298. doi: 10.1021/ic402254q
Y. Gloaguen, W. Jacobs, B. de Bruin, M. Lutz & J.I. van der Vlugt (2013). Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand. Inorganic Chemistry, 52 (4), 1682-1684. doi: 10.1021/ic302301h
M.G. Scheibel, Y. Wu, A.C. Stückl, L. Krause, E. Carl, D. Stalke, B. de Bruin & S. Schneider (2013). Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium. Journal of the American Chemical Society, 135 (47), 17719-17722. doi: 10.1021/ja409764j
A.J. Rosenthal, M. Vogt, B. de Bruin & H. Grützmacher (2013). A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond. European Journal of Inorganic Chemistry, 2013 (34), 5831-5835. doi: 10.1002/ejic.201301207
M.A.H. Moelands, S. Nijsse, E. Folkertsma, B. de Bruin, M. Lutz, A.L. Spek & R.J.M.K. Gebbink (2013). Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands. Inorganic Chemistry, 52 (13), 7394-7410. doi: 10.1021/ic400096e
E. Jansen, L.S. Jongbloed, D.S. Tromp, M. Lutz, B. de Bruin & C.J. Elsevier (2013). Ligand Effects on the Hydrogenation of Biomass-Inspired Substrates with Bifunctional Ru, Ir, and Rh Complexes. ChemSusChem, 6 (9), 1737-1744. doi: 10.1002/cssc.201300363
N.D. Paul, A. Chirila, H. Lu, X.P. Zhang & B. de Bruin (2013). Carbene Radicals in Cobalt(II)-Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes. Chemistry - A European Journal, 19 (39), 12953-12958. doi: 10.1002/chem.201301731
D.G.H. Hetterscheid, S.H. Chikkali, B. de Bruin & J.N.H. Reek (2013). Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins. ChemCatChem, 5 (10), 2785-2793. doi: 10.1002/cctc.201300092
J. Malberg, E. Lupton, E.M. Schnöckelborg, B. de Bruin, J. de Sutter, K. Meyer, F. Hartl & R. Wolf (2013). Synthesis and Electronic Structure of Dissymmetrical, Naphthalene-Bridged Sandwich Complexes [Cp ' Fe(mu-C10H8)MCp*](x) (x=0,+1; M = Fe, Ru; Cp ' = eta(5)-C5H2-1,2,4-tBu(3); Cp* = eta(5)-C5Me5). Organometallics, 32 (20), 6040-6052. doi: 10.1021/om4005862
M. Otte, P.F. Kuijpers, O. Troeppner, I. Ivanović-Burmazović, J.N.H. Reek & B. de Bruin (2013). Encapsulation of Metalloporphyrins in a Self-Assembled Cubic M8L6 Cage: A New Molecular Flask for Cobalt-Porphyrin-Catalysed Radical-Type Reactions. Chemistry - A European Journal, 19 (31), 10170-10178. doi: 10.1002/chem.201301411
Y. Gloaguen, L.M. Jongens, J.N.H. Reek, M. Lutz, B. de Bruin & J.I. van der Vlugt (2013). Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand. Organometallics, 32 (15), 4284-4291. doi: 10.1021/om400451y
S. Oldenhof, B. de Bruin, M. Lutz, M.A. Siegler, F.W. Patureau, J.I. van der Vlugt & J.N.H. Reek (2013). Base-Free Production of H-2 by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex. Chemistry - A European Journal, 19 (35), 11507-11511. doi: 10.1002/chem.201302230
N.M.G. Franssen, B. Ensing, M. Hegde, T.J. Dingemans, B. Norder, S. J. Picken, G. O. R. Alberda van Ekenstein, E.R.H. van Eck, J.A.A.W. Elemans, M. Vis, J.N.H. Reek & B. de Bruin (2013). On the "Tertiary Structure" of Poly-Carbenes; Self-Assembly of sp(3)-Carbon-Based Polymers into Liquid-Crystalline Aggregates. Chemistry - A European Journal, 19 (35), 11577-11589. doi: 10.1002/chem.201301403
N.M.G. Franssen, M. Finger, J.N.H. Reek & B. de Bruin (2013). Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane. Dalton Transactions, 42 (12), 4139-4152. doi: 10.1039/c2dt32584e[go to publisher's site]
V. Lyaskovskyy, R. J. A. van Dijk-Moes, S. Burck, W.I. Dzik, M. Lutz, A.W. Ehlers, J.C. Slootweg, B. de Bruin & K. Lammertsma (2013). Dibenzo[b,f]phosphepines: Novel Phosphane-Olefin Ligands for Transition Metals. Organometallics, 32 (2), 363-373. doi: 10.1021/om301012z
A.M. Kluwer, C. Simons, Q. Knijnenburg, J.I. van der Vlugt, B. de Bruin & J.N.H. Reek (2013). Catalyst recycling via specific non-covalent adsorption on modified silicas. Dalton Transactions, 42 (10), 3609-3616. doi: 10.1039/c2dt32047a[go to publisher's site]
N.M.G. Franssen, J.N.H. Reek & B. de Bruin (2013). A different route to functional polyolefins: olefin-carbene copolymerisation. Dalton Transactions, 42 (25), 9058-9068. doi: 10.1039/c3dt32941k[go to publisher's site]
M. Plois, W. Hujo, S. Grimme, C. Schwickert, E. Bill, B. de Bruin, R. Pöttgen & R. Wolf (2013). Open-Shell First-Row Transition-Metal Polyhydride Complexes Based on the fac-[RuH3(PR3)3]- Building Block. Angewandte Chemie, International Edition, 52 (4), 1314-1318. doi: 10.1002/anie.201205209
A.I. Olivos Suarez, V. Lyaskovskyy, J.N.H. Reek, J.I. van der Vlugt & B. de Bruin (2013). Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications. Angewandte Chemie, International Edition, 52 (48), 12510-12529. doi: 10.1002/anie.201301487

2012

A.I. Olivos Suarez, M.P. del Río, K. Remerie, J.N.H. Reek & B. de Bruin (2012). Rh-mediated C1-polymerization: copolymers from diazoesters and sulfoxonium ylides. ACS Catalysis, 2 (9), 2046-2059. doi: 10.1021/cs300363m
E.M. Reingruber, A. Chojnacka, E. Jellema, B. de Bruin, W. Buchberger & P.J. Schoenmakers (2012). Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate. Journal of Chromatography A, 1255, 259-266. doi: 10.1016/j.chroma.2012.02.059
K. Hindson & B. de Bruin (2012). Cooperative & redox non-innocent ligands in directing organometallic reactivity. European Journal of Inorganic Chemistry, 2012 (3), 340-342. doi: 10.1002/ejic.201290001
E.M. Schnoeckelborg, M.M. Khusniyarov, B. de Bruin, F. Hartl, T. Langer, M. Eul, S. Schulz, R. Poettgen & R. Wolf (2012). Unraveling the electronic structures of low-valent naphthalene and anthracene iron complexes: X-ray, spectroscopic, and density functional theory studies. Inorganic Chemistry, 51 (12), 6719-6730. doi: 10.1021/ic300366m
M.G. Scheibel, B. Askevold, F.W. Heinemann, E.J. Reijerse, B. de Bruin & S. Schneider (2012). Closed-shell and open-shell square-planar iridium nitrido complexes. Nature Chemistry, 4 (7), 552-558. doi: 10.1038/nchem.1368
A.J.C. Walters, O. Troeppner, I. Ivanovic-Burmazovic, C. Tejel, M.P. del Río, J.N.H. Reek & B. de Bruin (2012). Stereospecific carbene polymerization with oxygenated Rh(diene) species. Angewandte Chemie, International Edition, 51 (21), 5157-5161. doi: 10.1002/anie.201200069
A.J.C. Walters, E. Jellema, M. Finger, P. Aarnoutse, J.M.M. Smits, J.N.H. Reek & B. de Bruin (2012). Rh-mediated carbene polymerization: from multistep catalyst activation to alcohol-mediated chain-transfer. ACS Catalysis, 2 (2), 246-260. doi: 10.1021/cs200607s
C. Tejel, L. Asensio, M.P. del Río, B. de Bruin, J.A. Lopez & M.A. Ciriano (2012). Snapshots of a reversible metal-ligand two-electron transfer step involving compounds related by multiple types of isomerism. European Journal of Inorganic Chemistry, 2012 (3), 512-519. doi: 10.1002/ejic.201100868
V. Lyaskovskyy & B. de Bruin (2012). Redox non-innocent ligands: versatile new tools to control catalytic reactions. ACS Catalysis, 2 (2), 270-279. doi: 10.1021/cs200660v
N.M.G. Franssen, K. Rernerie, T. Macko, J.N.H. Reek & B. de Bruin (2012). Controlled synthesis of functional copolymers with blocky architectures via carbene polymerization. Macromolecules, 45 (9), 3711-3721. doi: 10.1021/ma300314q
M. Finger, M. Lutz, J.N.H. Reek & B. de Bruin (2012). Synthesis and reactivity of ester-functionalized 5-membered RhI-kappa 2-C,O-chelates and their relevance in Rh(cod)-mediated carbene polymerization. European Journal of Inorganic Chemistry, 2012 (9), 1437-1444. doi: 10.1002/ejic.201100981
B. de Bruin (2012). Special issue: cooperative & redox non-innocent ligands in directing organometallic reactivity. European Journal of Inorganic Chemistry, 2012 (3), 340-342. doi: 10.1002/ejic.201290001
S.H. Chikkali, R. Bellini, B. de Bruin, J.I. van der Vlugt & J.N.H. Reek (2012). Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins. Journal of the American Chemical Society, 134 (15), 6607-6616. doi: 10.1021/ja210117z
A. J. Boersma, B. de Bruin, B.L. Feringa & G. Roelfes (2012). Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis. Chemical Communications, 48 (18), 2394-2396. doi: 10.1039/c2cc17350f

2011

V. Lyaskovskyy, A.I. Olivos Suarez, H. Lu, H. Jiang, X.P. Zhang & B. de Bruin (2011). Mechanism of cobalt(II) porphyrin-catalyzed C−H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates. Journal of the American Chemical Society, 133 (31), 12264-12273. doi: 10.1021/ja204800a
G.V. Oshovsky, B. Hessen, J.N.H. Reek & B. de Bruin (2011). Electronic selectivity tuning in titanium(III)-catalyzed acetylene cross-dimerization reactions. Organometallics, 30 (22), 6067-6070. doi: 10.1021/om201008k
M. Vogt, B. de Bruin, H. Berke, M. Trincado & H. Grützmacher (2011). Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes. Chemical Science, 2 (4), 723-727. doi: 10.1039/c0sc00483a
H. Lu, W.I. Dzik, X. Xu, L. Wojtas, B. de Bruin & X.P. Zhang (2011). Experimental evidence for cobalt(III)-carbene radicals: key intermediates in cobalt(II)-based metalloradical cyclopropanation. Journal of the American Chemical Society, 133 (22), 8518-8521. doi: 10.1021/ja203434c
A.I. Olivos Suarez, H. Jiang, X.P. Zhang & B. de Bruin (2011). The radical mechanism of cobalt(II) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding. Dalton Transactions, 40 (21), 5697-5705. doi: 10.1039/c1dt10027k
W.I. Dzik, J.I. van der Vlugt, J.N.H. Reek & B. de Bruin (2011). Ligands that store and release electrons during catalysis. Angewandte Chemie, International Edition, 50 (15), 3356-3358. doi: 10.1002/anie.201006778
W.I. Dzik, L. Fuente Arruga, M.A. Siegler, A.L. Spek, J.N.H. Reek & B. de Bruin (2011). Open-shell organometallic [MII(dbcot(bislutidylamine)]2+ complexes (M = Rh, Ir): unexpected base-assisted reduction of the metal instead of amine ligand deprotonation. Organometallics, 30 (7), 1902-1913. doi: 10.1021/om101157r
M. Finger, J.N.H. Reek & B. de Bruin (2011). Role of β-h elimination in rhodium-mediated carbene insertion polymerization. Organometallics, 30 (5), 1094-1101. doi: 10.1021/om1011209
W.I. Dzik, S.E. Calvo, J.N.H. Reek, M. Lutz, M.A. Ciriano, C. Tejel, D.G.H. Hetterscheid & B. de Bruin (2011). Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+ for catalytic water oxidation. Organometallics, 30 (3), 372-374. doi: 10.1021/om100981v
P. Dydio, W.I. Dzik, M. Lutz, B. de Bruin & J.N.H. Reek (2011). Remote supramolecular control of catalyst selectivity in the hydroformylation of alkenes. Angewandte Chemie, International Edition, 50 (2), 396-400. doi: 10.1002/anie.201005173
N.M.G. Franssen, J.N.H. Reek & B. de Bruin (2011). Pd-mediated carbene polymerisation: activity of palladium(II) versus low-valent palladium. Polymer Chemistry, 2 (2), 422-431. doi: 10.1039/c0py00249f
W.I. Dzik, X.P. Zhang & B. de Bruin (2011). Redox noninnocence of carbene ligands: carbene radicals in (catalytic) C-C bond formation. Inorganic Chemistry, 50 (20), 9896-9903. doi: 10.1021/ic200043a
C. Tejel, L. Asensio, M.P. del Rio, B. de Bruin, J.A. Lopez & M.A. Ciriano (2011). Developing synthetic approaches with non-innocent metalloligands: easy access to Ir(I)/Pd(0) and Ir(I)/Pd(0)/Ir(I) cores. Angewandte Chemie, International Edition, 50 (38), 8839-8843. doi: 10.1002/anie.201104045
C. Tejel, M.P. del Río, L. Asensio, F.J. van den Bruele, M.A. Ciriano, N. Tsichlis i Spithas, D.G.H. Hetterscheid & B. de Bruin (2011). Cooperative double deprotonation of Bis(2-picolyl)amine leading to unexpected bimetallic mixed valence (M(-1), M(1)) rhodium and iIridium complexes. Inorganic Chemistry, 50 (16), 7524-7534. doi: 10.1021/ic200395m
R.C. Bauer, Y. Gloaguen, M. Lutz, J.N.H. Reek, B. de Bruin & J.I. van der Vlugt (2011). Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium. Dalton Transactions, 40 (35), 8822-8829. doi: 10.1039/C1DT10360A

2010

E. Kampert, J.C. Russcher, D.W. Boukhvalov, F.F.B.J. Janssen, J.M.M. Smits, R. de Gelder, B. de Bruin, P.C.M. Christianen, A.E. Rowan, M.I. Katsnelson, J.C. Maan & U. Zeitler (2010). Antiferromagnetic interactions in a distorted cubane-type tetranuclear manganese cluster. In Proceedings of the 2009 International Conference on Magnetism (ICM 2009) Vol. 200. Journal of Physics Conference Series (pp. 022022). Bristol: IOP Publishing.
F.F. Puschmann, J. Harmer, D. Stein, H. Rüegger, B. de Bruin & H. Grützmacher (2010). Electromeric rhodium radical complexes. Angewandte Chemie, International Edition, 49 (2), 385-389.
R. Wolf, N. Ghavtadze, K. Weber, E.M. Schnöckelborg, B. de Bruin, A.W. Ehlers & K. Lammertsma (2010). P-C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations. Dalton Transactions, 39 (6), 1453-1456.
J. Wassenaar, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek & J.I. van der Vlugt (2010). Activation of H2 by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand. Chemical Communications, 46 (8), 1232-1234.
J. Meeuwissen, R.J. Detz, A.J. Sandee, B. de Bruin & J.N.H. Reek (2010). Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions. Dalton Transactions, 39 (8), 1929-1931.
F.F. Puschmann, H. Grützmacher & B. de Bruin (2010). Rhodium(0) metalloradicals in binuclear C-H activation. Journal of the American Chemical Society, 132 (1), 73-75.
W.I. Dzik, C. Creusen, R. de Gelder, T.P.J. Peters, J.M.M. Smits & B. de Bruin (2010). Carbonyl complexes of rhodium with N-donor ligands: factors determining the formation of terminal versus bridging carbonyls. Organometallics, 29 (7), 1629-1641.
E. Jellema, A.L. Jongerius, J.N.H. Reek & B. de Bruin (2010). C1 polymerisation and related C-C bond forming ‘carbene insertion’ reactions. Chemical Society reviews, 39 (5), 1706-1723.
J. Meeuwissen, A.J. Sandee, B. de Bruin, M.A. Siegler, A.L. Spek & J.N.H. Reek (2010). Phosphinoureas: cooperative ligands in rhodium-catalyzed hydroformylation? On the possibility of a ligand-assisted reductive elimination of the aldehyde. Organometallics, 29 (11), 2413-2421.
A.I. Olivos Suarez, J.N.H. Reek & B. de Bruin (2010). Rhodium(I) mediated arylation of aldehydes with arylboronic acids under base and water free conditions: A computational study. Journal of Molecular Catalysis A-Chemical, 324 (1-2), 24-30.
E. Jellema, A.L. Jongerius, A.J.C. Walters, J.M.M. Smits, J.N.H. Reek & B. de Bruin (2010). Ligand design in Rh(diene)-mediated "carbene" polymerization; efficient synthesis of high-mass, highly stereoregular, and fully functionalized carbon-chain polymers. Organometallics, 29 (12), 2823-2826.
J. Wassenaar, B. de Bruin & J.N.H. Reek (2010). Rhodium-catalyzed asymmetric hydroformylation with Taddol-based IndolPhos ligands. Organometallics, 29 (12), 2767-2776.
J. Wassenaar, M.A. Siegler, A.L. Spek, B. de Bruin, J.N.H. Reek & J.I. van der Vlugt (2010). Versatile new C3-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu-I and Rh-I species and tune their reactivity. Inorganic Chemistry, 49 (14), 6495-6508.
J. Meeuwissen, R. Detz, A.J. Sandee, B. de Bruin, M.A. Siegler, A.L. Spek & J.N.H. Reek (2010). Ureaphosphanes as hybrid, anionic or supramolecular bidentate ligands for asymmetric hydrogenation reactions. European Journal of Inorganic Chemistry, 2992-2997.
W.I. Dzik, X. Xu, X.P. Zhang, J.N.H. Reek & B. de Bruin (2010). 'Carbene radicals' in Co-II(por)-catalyzed olefin cyclopropanation. Journal of the American Chemical Society, 132 (31), 10891-10902.
M. Tromp, G.P.F. van Strijdonck, S.S. van Berkel, A. van den Hoogenband, M.C. Feiters, B. de Bruin, S.G. Fiddy, A.M.J. van der Eerden, J.A. van Bokhoven, P.W.N.M. van Leeuwen & D.C. Koningsberger (2010). Multitechnique approach to reveal the mechanism of copper(II)-catalyzed arylation reactions. Organometallics, 29 (14), 3085-3097.
R. Wolf, A.W. Ehlers, M.M. Khusniyarov, F. Hartl, B. de Bruin, G.J. Long, F. Grandjean, F.M. Schappacher, R. Pöttgen, J.C. Slootweg, M. Lutz, A.L. Spek & K. Lammertsma (2010). Homoleptic Diphosphacyclobutadiene Complexes [M(η(4)-P2C2R2)(2]x- (M = Fe, Co; x=0, 1). Chemistry - A European Journal, 16 (48), 14322-14334. doi: 10.1002/chem.201001913
E. Jellema, A.L. Jongerius, G. Alberda van Ekenstein, S.D. Mookhoek, T.J. Dingemans, E.M. Reingruber, A. Chojnacka, P.J. Schoenmakers, R. Sprenkels, E.R.H. van Eck, J.N.H. Reek & B. de Bruin (2010). Rhodium-mediated stereospecific carbene polymerization: from homopolymers to random and block copolymers. Macromolecules, 43 (21), 8892-8903.
S.H. Chikkali, R. Bellini, G. Berthon-Gelloz, J.I. van der Vlugt, B. de Bruin & J.N.H. Reek (2010). Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes. Chemical Communications, 46 (8), 1244-1246.

2009

C. Tejel, M.P. del Río, M.A. Ciriano, E.J. Reijerse, F. Hartl, S. Záliš, D.G.H. Hetterscheid, N. Tsichlis i Spithas & B. de Bruin (2009). Ligand-centred reactivity of bis(picolyl)amine iridium: Sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand. Chemistry - A European Journal, 15 (44), 11878-11889.
D.G.H. Hetterscheid, J.I. van der Vlugt, B. de Bruin & J.N.H. Reek (2009). Water splitting by cooperative catalysis. Angewandte Chemie, International Edition, 48 (44), 8178-8181.
M. Rubio, E. Jellema, M.A. Siegler, A.L. Spek, J.N.H. Reek & B. de Bruin (2009). Supramolecular NHC ligands: On the influence of Zn-II-templates on the activity of Rh-I(cod) complexes in 'carbene polymerization'. Dalton Transactions, 8970-8976.
E. Kampert, F.F.B.J. Janssen, D.W. Boukhvalov, J.C. Russcher, J.M.M. Smits, R. de Gelder, B. de Bruin, P.C.M. Christianen, U. Zeitler, M.I. Katsnelson, J.C. Maan & A.E. Rowan (2009). Ligand-controlled magnetic interactions in Mn4 clusters. Inorganic Chemistry, 48 (24), 11903-11908.
W.I. Dzik, J.M.M. Smits, J.N.H. Reek & B. de Bruin (2009). Activation of carbon monoxide by (Me3tpa)Rh and (Me3tpa)Ir. Organometallics, 28 (6), 1631-1643.
F.W. Patureau, S. de Boer, M. Kuil, J. Meeuwissen, P.A.R. Breuil, M.A. Siegler, A.L. Spek, A.J. Sandee, B. de Bruin & J.N.H. Reek (2009). Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis. Journal of the American Chemical Society, 131 (19), 6683-6685.
G. Berthon-Gelloz, B. de Bruin, B. Tinant & I.E. Markó (2009). Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex. Angewandte Chemie, International Edition, 48 (17), 3161-3164.
B. de Bruin, W.I. Dzik, S. Li & B.B. Wayland (2009). Hydrogen-atom transfer in reactions of organic radicals with [Co-II(por)](center dot) (por = porphyrinato) and in subsequent addition of [Co(H)(por)] to olefins. Chemistry - A European Journal, 15 (17), 4312-4320.
R. Wolf, J.C. Slootweg, A.W. Ehlers, F. Hartl, B. de Bruin, M. Lutz, A.L. Spek & K. Lammertsma (2009). A phosphorus analogue of bis(eta(4)-cyclobutadiene)iron(0). Angewandte Chemie, International Edition, 48 (17), 3104-3107.

2008

C. Tejel, M.A. Ciriano, V. Passarelli, J.A. López & B. de Bruin (2008). Intervalent bis(mu-aziridinato)M-II-M-I complexes (M = Rh, Ir): Delocalized metallo-radicals or delocalized aminyl radicals? Chemistry - A European Journal, 14 (35), 10985-10998.
C. Tejel, M.A. Ciriano, M.P. del Río, F.J. van den Bruele, D.G.H. Hetterscheid, N. Tsichlis i Spithas & B. de Bruin (2008). Deprotonation induced ligand-to-metal electron transfer: Synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen. Journal of the American Chemical Society, 130 (18), 5844-5845.
C. Tejel, M.A. Ciriano, M.P. del Río, D.G.H. Hetterscheid, N. Tsichlis i Spithas, J.M.M. Smits & B. de Bruin (2008). Ligand oxidation of a deprotonated bis(picolyl)amine Ir-I(cod) complex. Chemistry - A European Journal, 14 (35), 10932-10936.
S. Li, B. de Bruin, C.-H. Peng, M. Fryd & B.B. Wayland (2008). Exchange of organic radicals with organo-cobalt complexes formed in the living radical polymerization of vinyl acetate. Journal of the American Chemical Society, 130 (40), 13373-13381.
K.S. Chan, X.Z. Li, W.I. Dzik & B. de Bruin (2008). Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh-II metalloradical: A combined experimental and theoretical study. Journal of the American Chemical Society, 130 (6), 2051-2061.
W.I. Dzik, J.N.H. Reek & B. de Bruin (2008). Selective C--C coupling of ir-ethene and ir-carbenoid radicals. Chemistry - A European Journal, 14 (25), 7594-7599.

2011

N.M.G. Franssen, A.J.C. Walters, J.N.H. Reek & B. de Bruin (2011). Carbene insertion into transition metal-carbon bonds: a new tool for catalytic C-C bond formation. Catalysis Science & Technology, 1 (2), 153-165. doi: 10.1039/C0CY00065E
W.I. Dzik & B. de Bruin (2011). Open-shell organometallics: reactivity at the ligand. In Ian.J.S. Fairlamb & Jason.M. Lynam (Eds.), Specialist Periodical Report Organometallic Chemistry (pp. 46-78). Cambridge: Royal Society of Chemistry.

2015

L.A. Berben, B. de Bruin & A.F. Heyduk (2015). Non-innocent ligands. (unknown, no 9). Cambridge, UK: Royal Soc Chemistry.
C. Rebreyend & B. de Bruin (2015). Photolytic N-2 Splitting: A Road to Sustainable NH3 Production? (unknown, no 1). WEINHEIM, GERMANY: WILEY-V C H VERLAG GMBH.
N. Khoenkhoen, B. de Bruin, J.N.H. Reek & W.I. Dzik (2015). Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers. European Journal of Inorganic Chemistry, 567-598. doi: 10.1002/ejic.201403041

2013

N.M.G. Franssen, J.N.H. Reek & B. de Bruin (2013). Synthesis of functional 'polyolefins': state of the art and remaining challenges. Chemical Society reviews, 42 (13), 5809-5832. doi: 10.1039/c3cs60032g[go to publisher's site]

2011

B. de Bruin (2011, April 17). Hoe maakt een spin een draad? Amsterdam, The Netherlands, Kinderlezing NEMO.

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