Photographer: foto Dirk Gillissen

prof. dr. B. (Bas) de Bruin


  • Faculty of Science
    HIMS
  • Visiting address
    Science Park A
    Science Park 904  Amsterdam
    Room number: E1.48
  • Postal address:
    Postbus  94720
    1090 GS  Amsterdam
  • B.deBruin@uva.nl
    T: 0205256495

2016

  • Broere, D. L. J., van Leest, N. P., de Bruin, B., Siegler, M. A., & van der Vlugt, J. I. (2016). Reversible Redox Chemistry and Catalytic C(sp(3))-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand. Inorganic Chemistry, 55(17), 8603-8611. DOI: 10.1021/acs.inorgchem.6b01192 [details]
  • Das, B. G., Chirila, A., Tromp, M., Reek, J. N. H., & de Bruin, B. (2016). Co-III-Carbene Radical Approach to Substituted 1H-Indenes. Journal of the American Chemical Society, 138(28), 8968-8975. DOI: 10.1021/jacs.6b05434 [details]
  • Dzik, W. I., Böhmer, W., & de Bruin, B. (2016). Multiple spin-state scenarios in organometallic reactivity. In M. Swart, & M. Costas (Eds.), Spin states in biochemistry and inorganic chemistry: influence on structure and reactivity (pp. 103-129). Chichester: Wiley. DOI: 10.1002/9781118898277.ch6 [details]
  • Goswami, M., Rebreyend, C., & de Bruin, B. (2016). Porphyrin Cobalt(III) "Nitrene Radical" Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y=0, NH). Molecules, 21(2), [242]. DOI: 10.3390/molecules21020242 [details] [PDF]
  • Jongbloed, L. S., de Bruin, B., Reek, J. N. H., Lutz, M., & van der Vlugt, J. I. (2016). Reversible cyclometalation at Rh-I as a motif for metal-ligand bifunctional bond activation and base-free formic acid dehydrogenation. Catalysis Science & Technology, 6(5), 1320-1327. DOI: 10.1039/c5cy01505g [details / files]
  • Leenders, S. H. A. M., Becker, R., Kumpulainen, T., de Bruin, B., Sawada, T., Kato, T., ... Reek, J. N. H. (2016). Selective Co-Encapsulation Inside an M6L4 Cage. CHEMISTRY-A EUROPEAN JOURNAL, 22(43), 15468-15474. DOI: 10.1002/chem.201603017 [details]
  • Tang, Z., Tejel, C., de Sarasa Buchaca, M. A., Lutz, M., van der Vlugt, J. I., & de Bruin, B. (2016). Reactivity of Me-pma Rh-I and Ir-I Complexes upon Deprotonation and Their Application in Catalytic Carbene Carbonylation Reactions. European Journal of Inorganic Chemistry, 2016(7), 963-974. DOI: 10.1002/ejic.201501302 [details]
  • de Bruin, B., Gualco, P., & Paul, N. D. (2016). Redox Non-innocent Ligands: Reactivity and Catalysis. In M. Stradiotto, & R. Lundgren (Eds.), Ligand Design In Metal Chemistry: Reactivity and Catalysis Weinheim: Wiley. [details]
  • van de Watering, F. F., Lutz, M., Dzik, W. I., de Bruin, B., & Reek, J. N. H. (2016). Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction. ChemCatChem, 8(17), 2752-2756. DOI: 10.1002/cctc.201600709 [details]
  • Broere, D. L. J., Plessius, R., Tory, J., Demeshko, S., de Bruin, B., Siegler, M. A., ... van der Vlugt, J. I. (2016). Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium. CHEMISTRY-A EUROPEAN JOURNAL, 22(39), 13965-13975. DOI: 10.1002/chem.201601900 [details]
  • Chakraborty, U., Muehldorf, B., van Velzen, N. J. C., de Bruin, B., Harder, S., & Wolf, R. (2016). [(CpNi)-Ni-Ar{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (Cp-Ar = C-5(C6H4-4-Et)(5), nacnac = HC[C(Me)N-(C6H3)-2,6-iPr(2)](2)). Inorganic Chemistry, 55(6), 3075-3078. DOI: 10.1021/acs.inorgchem.5b02979 [details]
  • Chakraborty, U., Urban, F., Mühldorf, B., Rebreyend, C., de Bruin, B., van Velzen, N., ... de Wolf, R. (2016). Accessing the (CpNi)-Ni-Ar(I) Synthon: Reactions with N-Heterocyclic Carbenes, TEMPO, Sulfur, and Selenium. Organometallics, 35(11), 1624-1631. DOI: 10.1021/acs.organomet.6b00084 [details]
  • Kluwer, A. M., Krafft, M. J., Hartenbach, I., de Bruin, B., & Kaim, W. (2016). Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)(2)]. Topics in Catalysis, 59(19-20), 1787-1792. DOI: 10.1007/s11244-016-0699-3 [details] [PDF]
  • Kuijpers, P. F., Otte, M., Duerr, M., Ivanovic-Burmazovic, I., Reek, J. N. H., & de Bruin, B. (2016). A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media. ACS Catalysis, 6(5), 3106-3112. DOI: 10.1021/acscatal.6b00283 [details]
  • Serrano, Á. L., Casado, M. A., Ciriano, M. A., de Bruin, B., López, J. A., & Tejel, C. (2016). Nucleophilicity and P-C bond formation reactions of a terminal phosphanido iridium complex. Inorganic Chemistry, 55(2), 828-839. DOI: 10.1021/acs.inorgchem.5b02301 [details]
  • Sikari, R., Sinha, S., Jash, U., Das, S., Brandão, P., de Bruin, B., & Paul, N. D. (2016). Deprotonation Induced Ligand Oxidation in a Ni-II Complex of a Redox Noninnocent N-1-(2-Aminophenyl)benzene-1,2-diamine and Its Use in Catalytic Alcohol Oxidation. Inorganic Chemistry, 55(12), 6114-6123. DOI: 10.1021/acs.inorgchem.6b00646 [details]

2015

  • Broere, D. L. J., Demeshko, S., de Bruin, B., Pidko, E. A., Reek, J. N. H., Siegler, M. A., ... van der Vlugt, J. I. (2015). Dinuclear Palladium Complexes with Two Ligand-Centered Radicals and a Single Bridging Ligand: Subtle Tuning of Magnetic Properties. Chemistry - A European Journal, 21(15), 5879-5886. DOI: 10.1002/chem.201500084 [details]
  • Broere, D. L. J., Metz, L. L., de Bruin, B., Reek, J. N. H., Siegler, M. A., & van der Vlugt, J. I. (2015). Redox-​Active Ligand-​Induced Homolytic Bond Activation. Angewandte Chemie, International Edition, 54(5), 1516-1520. DOI: 10.1002/anie.201410048 [details]
  • Drost, R. M., Rosar, V., Marta, S. D., Lutz, M., Demitri, N., Milani, B., ... Elsevier, C. J. (2015). Pd-catalyzed Z-selective semihydrogenation of alkynes: determining the type of active species. ChemCatChem, 7(14), 2095-2107. DOI: 10.1002/cctc.201500200 [details]
  • Drost, R. M., Broere, D. L. J., Hoogenboom, J., de Baan, S. N., Lutz, M., de Bruin, B., & Elsevier, C. J. (2015). Allylpalladium(II) Histidylidene Complexes and Their Application in Z-Selective Transfer Semihydrogenation of Alkynes. European Journal of Inorganic Chemistry, 2015(6), 982-996. DOI: 10.1002/ejic.201403104 [details]
  • Goswami, M., Chirila, A., Rebreyend, C., & de Bruin, B. (2015). EPR spectroscopy as a tool in homogeneous catalysis research. Topics in Catalysis, 58(12-13), 719-750. DOI: 10.1007/s11244-015-0414-9 [details] [PDF]
  • Goswami, M., Lyaskovskyy, V., Domingos, S. R., Buma, W. J., Woutersen, S., Troeppner, O., ... de Bruin, B. (2015). Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions. Journal of the American Chemical Society, 137(16), 5468-5479. DOI: 10.1021/jacs.5b01197 [details]
  • Gumrukcu, Y., de Bruin, B., & Reek, J. N. H. (2015). A Mechanistic Study of Direct Activation of Allylic Alcohols in Palladium Catalyzed Amination Reactions. Catalysts, 5(1), 349-365. DOI: 10.3390/catal5010349 [details] [PDF]
  • Jacobs, I., de Bruin, B., & Reek, J. N. H. (2015). Comparison of the Full Catalytic Cycle of Hydroformylation Mediated by Mono- and Bis-Ligated Triphenylphosphine-Rhodium Complexes by Using DFT Calculations. ChemCatChem, 7(11), 1708-1718. DOI: 10.1002/cctc.201500087 [details]
  • Jongbloed, L. S., de Bruin, B., Reek, J. N. H., Lutz, M., & van der Vlugt, J. I. (2015). Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex. Chemistry - A European Journal, 21(19), 7297-7305. DOI: 10.1002/chem.201406463 [details]
  • Korstanje, T. J., van der Vlugt, J. I., Elsevier, C. J., & de Bruin, B. (2015). Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst. Science, 350(6258), 298-302. DOI: 10.1126/science.aaa8938 [details]
  • Leenders, S. H. A. M., Gramage-Doria, R., de Bruin, B., & Reek, J. N. H. (2015). Transition metal catalysis in confined spaces. Chemical Society reviews, 44(2), 433-448. DOI: 10.1039/c4cs00192c [details] [PDF]
  • Li, P., Zaffaroni, R., de Bruin, B., & Reek, J. N. H. (2015). New Tetracobalt Cluster Compounds for Electrocatalytic Proton Reduction: Syntheses, Structures, and Reactivity. Chemistry - A European Journal, 21(10), 4027-4038. DOI: 10.1002/chem.201405052 [details]
  • Li, P., de Bruin, B., Reek, J. N. H., & Dzik, W. I. (2015). Photo- and thermal isomerization of (TP)Fe(CO)Cl-2 [TP = Bis(2-diphenylphosphinophenyl)phenylphosphine]. Organometallics, 34(20), 5009-5014. DOI: 10.1021/acs.organomet.5b00644 [details]
  • Oldenhof, S., Lutz, M., de Bruin, B., van der Vlugt, J. I., & Reek, J. N. H. (2015). Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand. Chemical Science, 6(2), 1027-1034. DOI: 10.1039/c4sc02555e [details / files]
  • Tang, Z., Otten, E., Reek, J. N. H., van der Vlugt, J. I., & de Bruin, B. (2015). Dynamic ligand reactivity in a rhodium pincer complex. Chemistry - A European Journal, 21(36), 12683-12693. DOI: 10.1002/chem.201501453 [details]
  • Tang, Z., Mandal, S., Paul, N. D., Lutz, M., Li, P., van der Vlugt, J. I., & de Bruin, B. (2015). Rhodium catalysed conversion of carbenes into ketenes and ketene imines using PNN pincer complexes. Organic Chemistry Frontiers, 2(12), 1561-1577. DOI: 10.1039/C5QO00287G [details / files]
  • Vreeken, V., Siegler, M. A., de Bruin, B., Reek, J. N. H., Lutz, M., & van der Vlugt, J. I. (2015). C-H Activation of Benzene by a Photoactivated Ni-II(azide): Formation of a Transient Nickel Nitrido Complex. Angewandte Chemie, International Edition, 54(24), 7055-7059. DOI: 10.1002/anie.201501437 [details]
  • Chan, Y. W., de Bruin, B., & Chan, K. S. (2015). Metalloradical-Catalyzed Selective 1,2-Rh-H Insertion into the Aliphatic Carbon-Carbon Bond of Cyclooctane. Organometallics, 34(12), 2849-2857. DOI: 10.1021/acs.organomet.5b00183 [details]
  • Geer, A. M., Serrano, Á. L., de Bruin, B., Ciriano, M. A., & Tejel, C. (2015). Terminal Phosphanido Rhodium Complexes Mediating Catalytic P-P and P-C Bond Formation. Angewandte Chemie, International Edition, 54(2), 472-475. DOI: 10.1002/anie.201407707 [details]
  • Lichtenberg, C., Adelhardt, M., Gianetti, T. L., Meyer, K., de Bruin, B., & Grützmacher, H. (2015). Low-valent iron mono-diazadiene compounds: electronic structure and catalytic application. ACS Catalysis, 5(10), 6230-6240. DOI: 10.1021/acscatal.5b01416 [details]
  • Lichtenberg, C., Viciu, L., Adelhardt, M., Sutter, J., Meyer, K., de Bruin, B., & Grützmacher, H. (2015). Low-Valent Iron(I) Amido Olefin Complexes as Promotors for Dehydrogenation Reactions. Angewandte Chemie, International Edition, 54(19), 5766-5771. DOI: 10.1002/anie.201411365 [details]
  • Lichtenberg, C., Viciu, L., Vogt, M., Rodríguez-Lugo, R. E., Adelhardt, M., Sutter, J., ... Grützmacher, H. (2015). Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster. Chemical Communications, 51(73), 13890-13893. DOI: 10.1039/c5cc04908c [details]
  • Majumdar, N., Paul, N. D., Mandal, S., de Bruin, B., & Wulff, W. D. (2015). Catalytic Synthesis of 2H-Chromenes. ACS Catalysis, 5(4), 2329-2366. DOI: 10.1021/acscatal.5b00026 [details]
  • Scheibel, M. G., Abbenseth, J., Kinauer, M., Heinemann, F. W., Würtele, C., de Bruin, B., & Schneider, S. (2015). Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species. Inorganic Chemistry, 54(19), 9290-9302. DOI: 10.1021/acs.inorgchem.5b00829 [details] [PDF]
  • Schwab, M. M., Himmel, D., Kacprzak, S., Kratzert, D., Radtke, V., Weis, P., ... Krossing, I. (2015). [Ni(cod)​2]​[Al(ORF)​4]​, a source for naked nickel(I) chemistry. Angewandte Chemie, International Edition, 54(49), 14706-14709. DOI: 10.1002/anie.201506475 [details]

2014

  • Broere, D. L. J., de Bruin, B., Reek, J. N. H., Lutz, M., Dechert, S., & van der Vlugt, J. I. (2014). Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex. Journal of the American Chemical Society, 136(33), 11574-11577. DOI: 10.1021/ja502164f [details]
  • Domingos, S. R., Huerta-Viga, A., Baij, L., Amirjalayer, S., Dunnebier, D. A. E., Walters, A. J. C., ... Woutersen, S. (2014). Amplified Vibrational Circular Dichroism as a Probe of Local Biomolecular Structure. Journal of the American Chemical Society, 136(9), 3530-3535. DOI: 10.1021/ja411405s [details]
  • Drost, R. M., Bouwens, T., van Leest, N. P., de Bruin, B., & Elsevier, C. J. (2014). Convenient Transfer Semihydrogenation Methodology for Alkynes Using a PdII-NHC Precatalyst. ACS Catalysis, 4(5), 1349-1357. DOI: 10.1021/cs4011502 [details]
  • Dydio, P., Detz, R. J., de Bruin, B., & Reek, J. (2014). Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular Catalysis. Journal of the American Chemical Society, 136(23), 8418-8429. DOI: 10.1021/ja503033q [details]
  • Gloaguen, Y., Rebreyend, C., Lutz, M., Kumar, P., Huber, M., van der Vlugt, J. I., ... de Bruin, B. (2014). An Isolated Nitridyl Radical-Bridged {Rh(N-center dot)Rh} Complex. Angewandte Chemie, International Edition, 53(26), 6814-6818. DOI: 10.1002/anie.201403445 [details]
  • Gumrukcu, Y., de Bruin, B., & Reek, J. N. H. (2014). Dehydrative Cross-Coupling Reactions of Allylic Alcohols with Olefins. Chemistry - A European Journal, 20(35), 10905-10909. DOI: 10.1002/chem.201404026 [details]
  • Gumrukcu, Y., de Bruin, B., & Reek, J. (2014). Hydrogen- Bond- Assisted Activation of Allylic Alcohols for Palladium- Catalyzed Coupling Reactions. ChemSusChem, 7(3), 890-896. DOI: 10.1002/cssc.201300723 [details]
  • Jansen, E., Lutz, M., de Bruin, B., & Elsevier, C. J. (2014). Charge-Delocalized κC-2,N-NHC-Amine Complexes of Rhodium, Iridium, and Ruthenium. Organometallics, 33(11), 2853-2861. DOI: 10.1021/om5003599 [details]
  • Li, P., Amirjalayer, S., Hartl, F., Lutz, M., de Bruin, B., Becker, R., ... Reek, J. N. H. (2014). Direct Probing of Photoinduced Electron Transfer in a Self-Assembled Biomimetic [2Fe2S]-Hydrogenase Complex Using Ultrafast Vibrational Spectroscopy. Inorganic Chemistry, 53(10), 5373-5383. DOI: 10.1021/ic500777d [details]
  • Oldenhof, S., Lutz, M., de Bruin, B., van der Vlugt, J. I., & Reek, J. N. H. (2014). Well-​defined BisMETAMORPhos PdI-​PdI complex: synthesis, structural characterization, and reactivity. Organometallics, 33(24), 7293-7298. DOI: 10.1021/om5010622 [details]
  • Oldenhof, S., Lutz, M., de Bruin, B., van der Vlugt, J. I., & Reek, J. N. H. (2014). Well-​defined BisMETAMORPhos PdI-​PdI complex: synthesis, structural characterization, and reactivity. Organometallics, 33(24), 7293-7298. DOI: 10.1021/om5010622 [details]
  • Otte, M., Kuijpers, P. F., Troeppner, O., Ivanović-Burmazović, I., Reek, J. N. H., & de Bruin, B. (2014). Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions. Chemistry - A European Journal, 20(17), 4880-4884. DOI: 10.1002/chem.201400055 [details]
  • Paul, N. D., Mandal, S., Otte, M., Cui, X., Zhang, X. P., & de Bruin, B. (2014). Metalloradical Approach to 2H-Chromenes. Journal of the American Chemical Society, 136(3), 1090-1096. DOI: 10.1021/ja4111336 [details]
  • Walters, A. J. C., Reek, J., & de Bruin, B. (2014). Computed Propagation and Termination Steps in [(Cycloocta-2,6-dien-1-yl)Rh-III(polymeryl)]+ Catalyzed Carbene Polymerization Reactions. ACS Catalysis, 4(5), 1376-1389. DOI: 10.1021/cs500160c [details]
  • Fang, H., Ling, Z., Lang, K., Brothers, P. J., de Bruin, B., & Fu, X. (2014). Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations. Chemical Science, 5(3), 916-921. DOI: 10.1039/c3sc52326h [details / files]
  • Pelties, S., Herrmann, D., de Bruin, B., Hartl, F., & Wolf, R. (2014). Selective P-4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides. Chemical Communications, 50(53), 7014-7016. DOI: 10.1039/c4cc02601b [details / files]

2013

  • Franssen, N. M. G., Ensing, B., Hegde, M., Dingemans, T. J., Norder, B., Picken, S. J., ... de Bruin, B. (2013). On the "Tertiary Structure" of Poly-Carbenes; Self-Assembly of sp(3)-Carbon-Based Polymers into Liquid-Crystalline Aggregates. Chemistry - A European Journal, 19(35), 11577-11589. DOI: 10.1002/chem.201301403 [details]
  • Franssen, N. M. G., Finger, M., Reek, J. N. H., & de Bruin, B. (2013). Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane. Dalton Transactions, 42(12), 4139-4152. DOI: 10.1039/c2dt32584e [details / files]
  • Franssen, N. M. G., Reek, J. N. H., & de Bruin, B. (2013). A different route to functional polyolefins: olefin-carbene copolymerisation. Dalton Transactions, 42(25), 9058-9068. DOI: 10.1039/c3dt32941k [details / files]
  • Gloaguen, Y., Jacobs, W., de Bruin, B., Lutz, M., & van der Vlugt, J. I. (2013). Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand. Inorganic Chemistry, 52(4), 1682-1684. DOI: 10.1021/ic302301h [details]
  • Gloaguen, Y., Jongens, L. M., Reek, J. N. H., Lutz, M., de Bruin, B., & van der Vlugt, J. I. (2013). Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand. Organometallics, 32(15), 4284-4291. DOI: 10.1021/om400451y [details]
  • Hetterscheid, D. G. H., Chikkali, S. H., de Bruin, B., & Reek, J. N. H. (2013). Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins. ChemCatChem, 5(10), 2785-2793. DOI: 10.1002/cctc.201300092 [details]
  • Jansen, E., Jongbloed, L. S., Tromp, D. S., Lutz, M., de Bruin, B., & Elsevier, C. J. (2013). Ligand Effects on the Hydrogenation of Biomass-Inspired Substrates with Bifunctional Ru, Ir, and Rh Complexes. ChemSusChem, 6(9), 1737-1744. DOI: 10.1002/cssc.201300363 [details]
  • Kluwer, A. M., Simons, C., Knijnenburg, Q., van der Vlugt, J. I., de Bruin, B., & Reek, J. N. H. (2013). Catalyst recycling via specific non-covalent adsorption on modified silicas. Dalton Transactions, 42(10), 3609-3616. DOI: 10.1039/c2dt32047a [details] [PDF]
  • Lyaskovskyy, V., van Dijk-Moes, R. J. A., Burck, S., Dzik, W. I., Lutz, M., Ehlers, A. W., ... Lammertsma, K. (2013). Dibenzo[b,f]phosphepines: Novel Phosphane-Olefin Ligands for Transition Metals. Organometallics, 32(2), 363-373. DOI: 10.1021/om301012z [details]
  • Oldenhof, S., de Bruin, B., Lutz, M., Siegler, M. A., Patureau, F. W., van der Vlugt, J. I., & Reek, J. N. H. (2013). Base-Free Production of H-2 by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex. Chemistry - A European Journal, 19(35), 11507-11511. DOI: 10.1002/chem.201302230 [details]
  • Olivos Suarez, A. I., Lyaskovskyy, V., Reek, J. N. H., van der Vlugt, J. I., & de Bruin, B. (2013). Complexes with Nitrogen-​Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications. Angewandte Chemie, International Edition, 52(48), 12510-12529. DOI: 10.1002/anie.201301487 [details]
  • Otte, M., Kuijpers, P. F., Troeppner, O., Ivanović-Burmazović, I., Reek, J. N. H., & de Bruin, B. (2013). Encapsulation of Metalloporphyrins in a Self-Assembled Cubic M8L6 Cage: A New Molecular Flask for Cobalt-Porphyrin-Catalysed Radical-Type Reactions. Chemistry - A European Journal, 19(31), 10170-10178. DOI: 10.1002/chem.201301411 [details]
  • Panman, M. R., Vos, J., Bocokić, V., Bellini, R., de Bruin, B., Reek, J., & Woutersen, S. (2013). Exchanging Conformations of a Hydroformylation Catalyst Structurally Characterized Using Two-Dimensional Vibrational Spectroscopy. Inorganic Chemistry, 52(24), 14294-14298. DOI: 10.1021/ic402254q [details]
  • Paul, N. D., Chirila, A., Lu, H., Zhang, X. P., & de Bruin, B. (2013). Carbene Radicals in Cobalt(II)-Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes. Chemistry - A European Journal, 19(39), 12953-12958. DOI: 10.1002/chem.201301731 [details]
  • Malberg, J., Lupton, E., Schnöckelborg, E. M., de Bruin, B., de Sutter, J., Meyer, K., ... Wolf, R. (2013). Synthesis and Electronic Structure of Dissymmetrical, Naphthalene-Bridged Sandwich Complexes [Cp ' Fe(mu-C10H8)MCp*](x) (x=0,+1; M = Fe, Ru; Cp ' = eta(5)-C5H2-1,2,4-tBu(3); Cp* = eta(5)-C5Me5). Organometallics, 32(20), 6040-6052. DOI: 10.1021/om4005862 [details]
  • Moelands, M. A. H., Nijsse, S., Folkertsma, E., de Bruin, B., Lutz, M., Spek, A. L., & Gebbink, R. J. M. K. (2013). Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands. Inorganic Chemistry, 52(13), 7394-7410. DOI: 10.1021/ic400096e [details]
  • Plois, M., Hujo, W., Grimme, S., Schwickert, C., Bill, E., de Bruin, B., ... Wolf, R. (2013). Open-Shell First-Row Transition-Metal Polyhydride Complexes Based on the fac-[RuH3(PR3)3]- Building Block. Angewandte Chemie, International Edition, 52(4), 1314-1318. DOI: 10.1002/anie.201205209 [details]
  • Rosenthal, A. J., Vogt, M., de Bruin, B., & Grützmacher, H. (2013). A Diolefin Diamide Rhodium(I) Complex and Its One-Electron Oxidation Resulting in a Two-Center, Three-Electron Rh-N Bond. European Journal of Inorganic Chemistry, 2013(34), 5831-5835. DOI: 10.1002/ejic.201301207 [details]
  • Scheibel, M. G., Wu, Y., Stückl, A. C., Krause, L., Carl, E., Stalke, D., ... Schneider, S. (2013). Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium. Journal of the American Chemical Society, 135(47), 17719-17722. DOI: 10.1021/ja409764j [details]

2012

  • Chikkali, S. H., Bellini, R., de Bruin, B., van der Vlugt, J. I., & Reek, J. N. H. (2012). Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins. Journal of the American Chemical Society, 134(15), 6607-6616. DOI: 10.1021/ja210117z [details]
  • Finger, M., Lutz, M., Reek, J. N. H., & de Bruin, B. (2012). Synthesis and reactivity of ester-functionalized 5-membered RhI-kappa 2-C,O-chelates and their relevance in Rh(cod)-mediated carbene polymerization. European Journal of Inorganic Chemistry, 2012(9), 1437-1444. DOI: 10.1002/ejic.201100981 [details]
  • Franssen, N. M. G., Rernerie, K., Macko, T., Reek, J. N. H., & de Bruin, B. (2012). Controlled synthesis of functional copolymers with blocky architectures via carbene polymerization. Macromolecules, 45(9), 3711-3721. DOI: 10.1021/ma300314q [details]
  • Lyaskovskyy, V., & de Bruin, B. (2012). Redox non-innocent ligands: versatile new tools to control catalytic reactions. ACS Catalysis, 2(2), 270-279. DOI: 10.1021/cs200660v [details]
  • Olivos Suarez, A. I., del Río, M. P., Remerie, K., Reek, J. N. H., & de Bruin, B. (2012). Rh-mediated C1-polymerization: copolymers from diazoesters and sulfoxonium ylides. ACS Catalysis, 2(9), 2046-2059. DOI: 10.1021/cs300363m [details]
  • Reingruber, E. M., Chojnacka, A., Jellema, E., de Bruin, B., Buchberger, W., & Schoenmakers, P. J. (2012). Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate. Journal of Chromatography A, 1255, 259-266. DOI: 10.1016/j.chroma.2012.02.059 [details]
  • Walters, A. J. C., Troeppner, O., Ivanovic-Burmazovic, I., Tejel, C., del Río, M. P., Reek, J. N. H., & de Bruin, B. (2012). Stereospecific carbene polymerization with oxygenated Rh(diene) species. Angewandte Chemie, International Edition, 51(21), 5157-5161. DOI: 10.1002/anie.201200069 [details]
  • Walters, A. J. C., Jellema, E., Finger, M., Aarnoutse, P., Smits, J. M. M., Reek, J. N. H., & de Bruin, B. (2012). Rh-mediated carbene polymerization: from multistep catalyst activation to alcohol-mediated chain-transfer. ACS Catalysis, 2(2), 246-260. DOI: 10.1021/cs200607s [details]
  • de Bruin, B. (2012). Cooperative & Redox Non-Innocent Ligands in Directing Organometallic Reactivity. Guest editorial. European Journal of Inorganic Chemistry, 2012(3), 340-342. DOI: 10.1002/ejic.201290001 [details]
  • Boersma, A. J., de Bruin, B., Feringa, B. L., & Roelfes, G. (2012). Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis. Chemical Communications, 48(18), 2394-2396. DOI: 10.1039/c2cc17350f [details]
  • Scheibel, M. G., Askevold, B., Heinemann, F. W., Reijerse, E. J., de Bruin, B., & Schneider, S. (2012). Closed-shell and open-shell square-planar iridium nitrido complexes. Nature Chemistry, 4(7), 552-558. DOI: 10.1038/NCHEM.1368 [details]
  • Schnoeckelborg, E. M., Khusniyarov, M. M., de Bruin, B., Hartl, F., Langer, T., Eul, M., ... Wolf, R. (2012). Unraveling the electronic structures of low-valent naphthalene and anthracene iron complexes: X-ray, spectroscopic, and density functional theory studies. Inorganic Chemistry, 51(12), 6719-6730. DOI: 10.1021/ic300366m [details]
  • Tejel, C., Asensio, L., del Río, M. P., de Bruin, B., Lopez, J. A., & Ciriano, M. A. (2012). Snapshots of a reversible metal-ligand two-electron transfer step involving compounds related by multiple types of isomerism. European Journal of Inorganic Chemistry, 2012(3), 512-519. DOI: 10.1002/ejic.201100868 [details]

2011

  • Bauer, R. C., Gloaguen, Y., Lutz, M., Reek, J. N. H., de Bruin, B., & van der Vlugt, J. I. (2011). Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium. Dalton Transactions, 40(35), 8822-8829. DOI: 10.1039/c1dt10360a [details]
  • Dydio, P., Dzik, W. I., Lutz, M., de Bruin, B., & Reek, J. N. H. (2011). Remote supramolecular control of catalyst selectivity in the hydroformylation of alkenes. Angewandte Chemie, International Edition, 50(2), 396-400. DOI: 10.1002/anie.201005173 [details]
  • Dzik, W. I., Calvo, S. E., Reek, J. N. H., Lutz, M., Ciriano, M. A., Tejel, C., ... de Bruin, B. (2011). Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+ for catalytic water oxidation. Organometallics, 30(3), 372-374. DOI: 10.1021/om100981v [details]
  • Dzik, W. I., Fuente Arruga, L., Siegler, M. A., Spek, A. L., Reek, J. N. H., & de Bruin, B. (2011). Open-shell organometallic [MII(dbcot(bislutidylamine)]2+ complexes (M = Rh, Ir): unexpected base-assisted reduction of the metal instead of amine ligand deprotonation. Organometallics, 30(7), 1902-1913. DOI: 10.1021/om101157r [details]
  • Dzik, W. I., Zhang, X. P., & de Bruin, B. (2011). Redox noninnocence of carbene ligands: carbene radicals in (catalytic) C-C bond formation. Inorganic Chemistry, 50(20), 9896-9903. DOI: 10.1021/ic200043a [details]
  • Dzik, W. I., van der Vlugt, J. I., Reek, J. N. H., & de Bruin, B. (2011). Ligands that store and release electrons during catalysis. Angewandte Chemie, International Edition, 50(15), 3356-3358. DOI: 10.1002/anie.201006778 [details]
  • Finger, M., Reek, J. N. H., & de Bruin, B. (2011). Role of β-h elimination in rhodium-mediated carbene insertion polymerization. Organometallics, 30(5), 1094-1101. DOI: 10.1021/om1011209 [details]
  • Franssen, N. M. G., Reek, J. N. H., & de Bruin, B. (2011). Pd-mediated carbene polymerisation: activity of palladium(II) versus low-valent palladium. Polymer Chemistry, 2(2), 422-431. DOI: 10.1039/c0py00249f [details]
  • Lyaskovskyy, V., Olivos Suarez, A. I., Lu, H., Jiang, H., Zhang, X. P., & de Bruin, B. (2011). Mechanism of cobalt(II) porphyrin-catalyzed C−H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates. Journal of the American Chemical Society, 133(31), 12264-12273. DOI: 10.1021/ja204800a [details]
  • Olivos Suarez, A. I., Jiang, H., Zhang, X. P., & de Bruin, B. (2011). The radical mechanism of cobalt(II) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding. Dalton Transactions, 40(21), 5697-5705. DOI: 10.1039/c1dt10027k [details]
  • Lu, H., Dzik, W. I., Xu, X., Wojtas, L., de Bruin, B., & Zhang, X. P. (2011). Experimental evidence for cobalt(III)-carbene radicals: key intermediates in cobalt(II)-based metalloradical cyclopropanation. Journal of the American Chemical Society, 133(22), 8518-8521. DOI: 10.1021/ja203434c [details]
  • Oshovsky, G. V., Hessen, B., Reek, J. N. H., & de Bruin, B. (2011). Electronic selectivity tuning in titanium(III)-catalyzed acetylene cross-dimerization reactions. Organometallics, 30(22), 6067-6070. DOI: 10.1021/om201008k [details]
  • Tejel, C., Asensio, L., del Rio, M. P., de Bruin, B., Lopez, J. A., & Ciriano, M. A. (2011). Developing synthetic approaches with non-innocent metalloligands: easy access to Ir(I)/Pd(0) and Ir(I)/Pd(0)/Ir(I) cores. Angewandte Chemie, International Edition, 50(38), 8839-8843. DOI: 10.1002/anie.201104045 [details]
  • Tejel, C., del Río, M. P., Asensio, L., van den Bruele, F. J., Ciriano, M. A., Tsichlis i Spithas, N., ... de Bruin, B. (2011). Cooperative double deprotonation of Bis(2-picolyl)amine leading to unexpected bimetallic mixed valence (M(-1), M(1)) rhodium and iIridium complexes. Inorganic Chemistry, 50(16), 7524-7534. DOI: 10.1021/ic200395m [details]
  • Vogt, M., de Bruin, B., Berke, H., Trincado, M., & Grützmacher, H. (2011). Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes. Chemical Science, 2(4), 723-727. DOI: 10.1039/c0sc00483a [details]

2010

  • Chikkali, S. H., Bellini, R., Berthon-Gelloz, G., van der Vlugt, J. I., de Bruin, B., & Reek, J. N. H. (2010). Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes. Chemical Communications, 46(8), 1244-1246. DOI: 10.1039/b924046b [details]
  • Dzik, W. I., Creusen, C., de Gelder, R., Peters, T. P. J., Smits, J. M. M., & de Bruin, B. (2010). Carbonyl complexes of rhodium with N-donor ligands: factors determining the formation of terminal versus bridging carbonyls. Organometallics, 29(7), 1629-1641. DOI: 10.1021/om901023n [details]
  • Dzik, W. I., Xu, X., Zhang, X. P., Reek, J. N. H., & de Bruin, B. (2010). 'Carbene radicals' in Co-II(por)-catalyzed olefin cyclopropanation. Journal of the American Chemical Society, 132(31), 10891-10902. DOI: 10.1021/ja103768r [details]
  • Jellema, E., Jongerius, A. L., Alberda van Ekenstein, G., Mookhoek, S. D., Dingemans, T. J., Reingruber, E. M., ... de Bruin, B. (2010). Rhodium-mediated stereospecific carbene polymerization: from homopolymers to random and block copolymers. Macromolecules, 43(21), 8892-8903. DOI: 10.1021/ma101792v [details]
  • Jellema, E., Jongerius, A. L., Reek, J. N. H., & de Bruin, B. (2010). C1 polymerisation and related C-C bond forming ‘carbene insertion’ reactions. Chemical Society reviews, 39(5), 1706-1723. DOI: 10.1039/b911333a [details]
  • Jellema, E., Jongerius, A. L., Walters, A. J. C., Smits, J. M. M., Reek, J. N. H., & de Bruin, B. (2010). Ligand design in Rh(diene)-mediated "carbene" polymerization; efficient synthesis of high-mass, highly stereoregular, and fully functionalized carbon-chain polymers. Organometallics, 29(12), 2823-2826. DOI: 10.1021/om100226d [details]
  • Meeuwissen, J., Detz, R., Sandee, A. J., de Bruin, B., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Ureaphosphanes as hybrid, anionic or supramolecular bidentate ligands for asymmetric hydrogenation reactions. European Journal of Inorganic Chemistry, (19), 2992-2997. DOI: 10.1002/ejic.201000213 [details]
  • Meeuwissen, J., Detz, R. J., Sandee, A. J., de Bruin, B., & Reek, J. N. H. (2010). Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions. Dalton Transactions, 39(8), 1929-1931. DOI: 10.1039/b926043a [details]
  • Meeuwissen, J., Sandee, A. J., de Bruin, B., Siegler, M. A., Spek, A. L., & Reek, J. N. H. (2010). Phosphinoureas: cooperative ligands in rhodium-catalyzed hydroformylation? On the possibility of a ligand-assisted reductive elimination of the aldehyde. Organometallics, 29(11), 2413-2421. DOI: 10.1021/m901028z [details]
  • Olivos Suarez, A. I., Reek, J. N. H., & de Bruin, B. (2010). Rhodium(I) mediated arylation of aldehydes with arylboronic acids under base and water free conditions: A computational study. Journal of Molecular Catalysis A-Chemical, 324(1-2), 24-30. DOI: 10.1016/j.molcata.2010.03.002 [details]
  • Wassenaar, J., Siegler, M. A., Spek, A. L., de Bruin, B., Reek, J. N. H., & van der Vlugt, J. I. (2010). Versatile new C3-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu-I and Rh-I species and tune their reactivity. Inorganic Chemistry, 49(14), 6495-6508. DOI: 10.1021/ic100221w [details]
  • Wassenaar, J., de Bruin, B., Siegler, M. A., Spek, A. L., Reek, J. N. H., & van der Vlugt, J. I. (2010). Activation of H2 by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand. Chemical Communications, 46(8), 1232-1234. DOI: 10.1039/b917632b [details]
  • Wassenaar, J., de Bruin, B., & Reek, J. N. H. (2010). Rhodium-catalyzed asymmetric hydroformylation with Taddol-based IndolPhos ligands. Organometallics, 29(12), 2767-2776. DOI: 10.1021/om100236v [details]
  • Kampert, E., Russcher, J. C., Boukhvalov, D. W., Janssen, F. F. B. J., Smits, J. M. M., de Gelder, R., ... Zeitler, U. (2010). Antiferromagnetic interactions in a distorted cubane-type tetranuclear manganese cluster. Journal of Physics. Conference Series, 200, 022022. DOI: 10.1088/1742-6596/200/2/022022 [details] [PDF]
  • Puschmann, F. F., Grützmacher, H., & de Bruin, B. (2010). Rhodium(0) metalloradicals in binuclear C-H activation. Journal of the American Chemical Society, 132(1), 73-75. DOI: 10.1021/ja909022p [details]
  • Puschmann, F. F., Harmer, J., Stein, D., Rüegger, H., de Bruin, B., & Grützmacher, H. (2010). Electromeric rhodium radical complexes. Angewandte Chemie, International Edition, 49(2), 385-389. DOI: 10.1002/anie.200903201 [details]
  • Tromp, M., van Strijdonck, G. P. F., van Berkel, S. S., van den Hoogenband, A., Feiters, M. C., de Bruin, B., ... Koningsberger, D. C. (2010). Multitechnique approach to reveal the mechanism of copper(II)-catalyzed arylation reactions. Organometallics, 29(14), 3085-3097. DOI: 10.1021/om9010643 [details]
  • Wolf, R., Ghavtadze, N., Weber, K., Schnöckelborg, E. M., de Bruin, B., Ehlers, A. W., & Lammertsma, K. (2010). P-C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations. Dalton Transactions, 39(6), 1453-1456. DOI: 10.1039/b923663p [details]
  • Wolf, R., Ehlers, A. W., Khusniyarov, M. M., Hartl, F., de Bruin, B., Long, G. J., ... Lammertsma, K. (2010). Homoleptic Diphosphacyclobutadiene Complexes [M(η(4)-P2C2R2)(2]x- (M = Fe, Co; x=0, 1). Chemistry - A European Journal, 16(48), 14322-14334. DOI: 10.1002/chem.201001913 [details]

2009

  • Berthon-Gelloz, G., de Bruin, B., Tinant, B., & Markó, I. E. (2009). Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex. Angewandte Chemie, International Edition, 48(17), 3161-3164. DOI: 10.1002/anie.200900435 [details]
  • Dzik, W. I., Smits, J. M. M., Reek, J. N. H., & de Bruin, B. (2009). Activation of carbon monoxide by (Me3tpa)Rh and (Me3tpa)Ir. Organometallics, 28(6), 1631-1643. DOI: 10.1021/om801142y [details]
  • Hetterscheid, D. G. H., van der Vlugt, J. I., de Bruin, B., & Reek, J. N. H. (2009). Water splitting by cooperative catalysis. Angewandte Chemie, International Edition, 48(44), 8178-8181. DOI: 10.1002/anie.200902455 [details]
  • Patureau, F. W., de Boer, S., Kuil, M., Meeuwissen, J., Breuil, P. A. R., Siegler, M. A., ... Reek, J. N. H. (2009). Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis. Journal of the American Chemical Society, 131(19), 6683-6685. DOI: 10.1021/ja9024879 [details]
  • Rubio, M., Jellema, E., Siegler, M. A., Spek, A. L., Reek, J. N. H., & de Bruin, B. (2009). Supramolecular NHC ligands: On the influence of Zn-II-templates on the activity of Rh-I(cod) complexes in 'carbene polymerization'. Dalton Transactions, (41), 8970-8976. DOI: 10.1039/b911339h [details]
  • de Bruin, B., Dzik, W. I., Li, S., & Wayland, B. B. (2009). Hydrogen-atom transfer in reactions of organic radicals with [Co-II(por)](center dot) (por = porphyrinato) and in subsequent addition of [Co(H)(por)] to olefins. Chemistry - A European Journal, 15(17), 4312-4320. DOI: 10.1002/chem.200802022 [details]
  • Kampert, E., Janssen, F. F. B. J., Boukhvalov, D. W., Russcher, J. C., Smits, J. M. M., de Gelder, R., ... Rowan, A. E. (2009). Ligand-controlled magnetic interactions in Mn4 clusters. Inorganic Chemistry, 48(24), 11903-11908. DOI: 10.1021/ic901930w [details]
  • Tejel, C., del Río, M. P., Ciriano, M. A., Reijerse, E. J., Hartl, F., Záliš, S., ... de Bruin, B. (2009). Ligand-centred reactivity of bis(picolyl)amine iridium: Sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand. Chemistry - A European Journal, 15(44), 11878-11889. DOI: 10.1002/chem.200901017 [details]
  • Wolf, R., Slootweg, J. C., Ehlers, A. W., Hartl, F., de Bruin, B., Lutz, M., ... Lammertsma, K. (2009). A phosphorus analogue of bis(eta(4)-cyclobutadiene)iron(0). Angewandte Chemie, International Edition, 48(17), 3104-3107. DOI: 10.1002/anie.200805193 [details]
  • Wolf, R., Slootweg, J. C., Ehlers, A. W., Hartl, F., de Bruin, B., Lutz, M., ... Lammertsma, K. (2009). Cover picture: A phosphorus analogue of bis(eta(4)-cyclobutadiene)iron(0). Angewandte Chemie, International Edition, 48(17), 2993. DOI: 10.1002/anie.200990084 [details]

2008

  • Dzik, W. I., Reek, J. N. H., & de Bruin, B. (2008). Selective C--C coupling of ir-ethene and ir-carbenoid radicals. Chemistry - A European Journal, 14(25), 7594-7599. DOI: 10.1002/chem.200800262 [details]
  • Chan, K. S., Li, X. Z., Dzik, W. I., & de Bruin, B. (2008). Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh-II metalloradical: A combined experimental and theoretical study. Journal of the American Chemical Society, 130(6), 2051-2061. DOI: 10.1021/ja078157f [details]
  • Li, S., de Bruin, B., Peng, C-H., Fryd, M., & Wayland, B. B. (2008). Exchange of organic radicals with organo-cobalt complexes formed in the living radical polymerization of vinyl acetate. Journal of the American Chemical Society, 130(40), 13373-13381. DOI: 10.1021/ja804010h [details]
  • Tejel, C., Ciriano, M. A., Passarelli, V., López, J. A., & de Bruin, B. (2008). Intervalent bis(mu-aziridinato)M-II-M-I complexes (M = Rh, Ir): Delocalized metallo-radicals or delocalized aminyl radicals? Chemistry - A European Journal, 14(35), 10985-10998. DOI: 10.1002/chem.200801615 [details]
  • Tejel, C., Ciriano, M. A., del Río, M. P., van den Bruele, F. J., Hetterscheid, D. G. H., Tsichlis i Spithas, N., & de Bruin, B. (2008). Deprotonation induced ligand-to-metal electron transfer: Synthesis of a mixed-valence Rh(-I,I) dinuclear compound and its reaction with dioxygen. Journal of the American Chemical Society, 130(18), 5844-5845. DOI: 10.1021/ja711495v [details]
  • Tejel, C., Ciriano, M. A., del Río, M. P., Hetterscheid, D. G. H., Tsichlis i Spithas, N., Smits, J. M. M., & de Bruin, B. (2008). Ligand oxidation of a deprotonated bis(picolyl)amine Ir-I(cod) complex. Chemistry - A European Journal, 14(35), 10932-10936. DOI: 10.1002/chem.200801162 [details]

2015

  • Berben, L. A., de Bruin, B., & Heyduk, A. F. (2015). Non-innocent ligands. Chemical Communications, 51(9), 1553-1554. DOI: 10.1039/c4cc90480j [details] [PDF]

2011

  • Dzik, W. I., & de Bruin, B. (2011). Open-shell organometallics: reactivity at the ligand. In I. J. S. Fairlamb, & J. M. Lynam (Eds.), Specialist Periodical Report Organometallic Chemistry (pp. 46-78). Cambridge: Royal Society of Chemistry. DOI: 10.1039/9781849732802-00046 [details]
  • Franssen, N. M. G., Walters, A. J. C., Reek, J. N. H., & de Bruin, B. (2011). Carbene insertion into transition metal-carbon bonds: a new tool for catalytic C-C bond formation. Catalysis Science & Technology, 1(2), 153-165. DOI: 10.1039/c0cy00065e [details]

2015

  • Rebreyend, C., & de Bruin, B. (2015). Photolytic N-2 Splitting: A Road to Sustainable NH3 Production? Angewandte Chemie, International Edition, 54(1), 42-44. DOI: 10.1002/anie.201409727 [details]
  • Khoenkhoen, N., de Bruin, B., Reek, J. N. H., & Dzik, W. I. (2015). Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers. European Journal of Inorganic Chemistry, 2015(4), 567-598. DOI: 10.1002/ejic.201403041 [details]

2013

  • Franssen, N. M. G., Reek, J. N. H., & de Bruin, B. (2013). Synthesis of functional 'polyolefins': state of the art and remaining challenges. Chemical Society reviews, 42(13), 5809-5832. DOI: 10.1039/c3cs60032g [details] [PDF]

2017

  • Kuijpers, P. F. (2017). Controlling radical-type reactivity with transition metals and supramolecular cages [details / files]

Award

  • de Bruin, B. (2016): NWO TOP grant.

Keynote / Invited lecture

  • de Bruin, B. (speaker) (17-4-2011): Hoe maakt een spin een draad?, Kinderlezing NEMO, Amsterdam, The Netherlands.
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