Fotograaf: onbekend

mw. dr. S. (Stefania) Grecea


  • Faculteit der Natuurwetenschappen, Wiskunde en Informatica
    HIMS
  • Bezoekadres
    Science Park A
    Science Park 904  Kamernummer: C2.241
  • Postadres:
    Postbus  94720
    1090 GS  Amsterdam
  • s.grecea@uva.nl
    T: 0205257245

EDUCATION:

1997–2002      PhD in Inorganic Chemistry, University of Bucharest.

1996–1997      MSc in Applied Chemistry, Technical University of Bucharest.

1991–1996      BSc in Chemistry, University of Bucharest.

RESEARCH EXPERIENCE:

2011-               Assistant Professor at the University of Amsterdam. Leader of the Inorganic Materials team at the Heterogeneous Catalysis and Sustainable Chemistry group.

2009–2011      Senior Researcher at the University of Amsterdam. Supervising one PhD student in the CatchBio project, Conversion of lignin to value-added products with heterogeneous catalysts.

2008–2009      Guest Researcher at the University of Leiden. Supervising one PhD student working on Synthetic strategies for magnetic molecular materials.

2005–2008      NWO Veni Laureate at the University of Leiden. Developed a building-block synthetic strategy for making magnetic and optical metal-organic frameworks.

2005                Associate Researcher at Pierre and Marie Curie University - Paris VI. Developed efficient synthetic routes for the synthesis of multifunctional molecular materials.

2004                Visiting Scientist at Liege University. Studied Mössbauer spectroscopy for characterizing biomimetic compounds.

2001–2005      Postdoctoral Researcher at the University of Leiden. Designed biomimetic compounds for oxidation catalysis.

1999                PhD Fellow at University of Bordeaux I. Developed synthetic strategies for molecular magnetic materials.

TEACHING EXPERIENCE:

2011-              University of Amsterdam. Lecturer in Building-blocks of Chemistry, Molecule & Life, Functional Materials, Green & Industrial Chemistry, Heterogeneous Catalysis, Catalysis for Sustainable Energy.

2004–2008      University of Leiden. Lecturer in Bioinorganic Chemistry and Physical Methods in Inorganic Chemistry.

2007                Holland Research School of Molecular Chemistry. Invited lecturer on Electron Paramagnetic Resonance and Magnetic Susceptibility.

2001–2005      University of Bucharest. Lecturer in Structural Inorganic Chemistry, Coordination Chemistry and Supramolecular Chemistry.

1998–2001      University of Bucharest. Teaching Assistant in Inorganic Chemistry.

78. Dual-mode humidity detection using a lanthanide-based metalorganic framework: towards multifunctional humidity sensors. Y. Gao, P. Jing, N. Yan, M. Hilbers, H. Zhang, G.Rothenberg, S.Tanase, Chem. Commun., 2017, DOI: 10.1039/C7CC01122A.

77. Water-dispersible silica-coated upconverting liposomes: Can a thin silica layer protect TTA-UC against oxygen quenching? S. H. C. Askes, V. C. Leeuwenburgh, W. Pomp, H. Arjmandi-Tash, S. Tanase, T. Schmidtand, S. Bonnet, ACS Biomater. Sci. Eng., 2017, DOI: 10.1021/acsbiomaterials.6b00678.

76. Lanthanide-based metal organic frameworks: synthetic strategies and catalytic applications. C. Pagis, M. Ferbinteanu, G. Rothenberg, S. Tanase, ACS Catalysis, 2016, 6, 6063-6072.

75. A rational synthesis of hierarchically porous, N-doped carbon from Mg-based MOFs: Understanding the link between nitrogen content and oxygen reduction electrocatalysis. D. Eisenberg, W. Stroek, N. J. Geels, S. Tanase, M. Ferbinteanu, S. J. Teat, P. Mettraux, N. Yan, G. Rothenberg Phys. Chem. Chem. Phys., 2016, 18, 20778-20783.

74. Mixed-lanthanoid metal-organic framework for ratiometric cryogenic temperature sensing. X. Liu, S. Akerboom, M. de Jong, I. Mutikainen, S. Tanase, A. Meijerink, E. Bouwman Inorg. Chem., 2015, 54, 11323-11329.

73. A novel one-dimensional chain built of vanadyl ions and pyrazine-2,5-dicarboxylate. M. Lankelma, J. de Boer, M. Ferbinteanu, A. L. Dantas Ramos, R. Tanasa, G. Rothenberg, S. Tanase, Dalton Trans., 2015, 44, 11380-11387.

72. High proton conductivity in cyanide-bridged metal-organic frameworks: understanding the role of water. Y. Gao, R. Broersen, W. Hageman, N. Yan, M.C. Mittelmeijer-Hazeleger, G. Rothenberg, S. Tanase J. Mater. Chem. A, 2015, 3, 22347-22352.

71. Metal-organic frameworks with d-f cyanide bridges: structural diversity, bonding regime and magnetism. M. Ferbinteanu, F. Cimpoesu, S. Tanase, Structure and bonding, 2015, 163, 185-230.

70. Lignin solubilisation and gentle fractionation in liquid ammonia. Z.I. Strassberger, P.L.K. Prinsen, F. van der Klis, D.S. van Es, S. Tanase, G. Rothenberg Green Chem., 2015, 17, 325-334.

69. Highly selective water adsorption in a lanthanum metal-organic framework. R. Plessius, R. Kromhout, A.L.D. Ramos, M. Ferbinteanu, M.C. Mittelmeijer-Hazeleger, R. Krishna, G. Rothenberg, S. Tanase Chem. Eur. J., 2014, 20, 7922-7925.

68. Metal-organic frameworks and their application in catalysis. A.L. Dantas Ramos, S. Tanase, G. Rothenberg Quim. Nova, 37, 123-133.

67. The pros and cons of lignin valorisation in an integrated biorefinery. Z. Strassberger, S. Tanase, G. Rothenberg RSC Advances, 2014, 4, 25310-25318.

66. Catalytic cleavage of lignin ß-O-4 link mimics using copper on alumina and magnesia-alumina. Z. Strassberger, A.H. Alberts, M.J. Louwerse, S. Tanase, G. Rothenberg Green Chem., 2013, 15, 768-774.

65. Synthesis, characterization and testing of a new V2O5/Al2O3−MgO catalyst for butene dehydrogenation and limonene oxidation. Z. Strassberger, E.V. Ramos-Fernandez, A. Boonstra, R. Jorna, S. Tanase, G. Rothenberg Dalton Trans., 2013, 42, 5546-5553.

64. Poly(vinylidene fluoride)/nickel nanocomposites from semicrystalline block copolymer precursors. V. S. D. Voet, M. Tichelaar, S. Tanase, M. C. Mittelmijer-Hazeleger, G. Ten Brinke, K. Loos Nanoscale, 2013, 5, 184-192.

63. Mononuclear and dinuclear manganese compounds stabilized by supramolecular interaction. M. Viciano-Chumillas, M. Gimenez-Marques, S. Tanase, I. Mutikainen, U. Turpeinen, J. M. M. Smits, R. de Gelder, L.J. de Jongh, J. Reedijk Dalton Trans., 2012, 41, 10249-10257.

62. Realization of the one-dimensional anisotropic XY model in a Tb(III)-W(V) chain compound. E. Pasca, T. Roscilde, M. Evangelisti, E. Burzuri, F. Luis, L.J. de Jongh, S. Tanase Phys. Rev. B, 2012, 85, 184434-184440.

61. Sulfated zirconia as a robust superacid catalyst for multiproduct fatty acid esterification. M. L. Grecea, A. C. Dimian, S. Tanase, V. Subbiah, G. Rothenberg Catal. Sci. Technol., 2012, 2, 1500-1506.

60. A dinuclear manganese(III) and a rare pentanuclear manganese(III) compound with a phenol-pyrazole ligand. M. Viciano-Chumillas, S. Tanase, I. Mutikainen, U. Turpeinen, L.J. de Jongh, J. Reedijk Polyhedron, 2012, 38, 178-184.

59. Structure and magnetism in Fe-Gd based dinuclear and chain systems. The interplay of weak exchange coupling and zero field splitting effects. M. Ferbinteanu, F. Cimpoesu, M. A. Girtu, C. Enachescu, S. Tanase Inorg. Chem., 2012, 51, 40-50.

58. Rationalization of the lanthanide íon driven magnetic properties in a series of 4f-5d cyano-bridged chains. S. Tanase, C. Ferbinteanu, M. Cimpoesu Inorg. Chem., 2011, 50, 9678-9687.

57. A facile building-block synthesis of multifunctional lanthanide MOFs. S. Tanase, M. C. Mittelmeijer, G. Rothenberg, C. Mathoniere, V. Jubera, J. M. M. Smits, R. de Gelder J. Mater. Chem., 2011, 21, 15544-15551.

56. Short-range correlations in d-f cyanide-bridged assemblies with XY and XY-Heisenberg anisotropy. S. Tanase, M. Evangelisti, L. J. de Jongh Dalton Trans., 2011, 40, 8407-8413.

55. Reductive dealkylation of anisole and phenetole: towards practical lignin conversion. Z. Strassberger, S. Tanase, G. Rothenberg Eur. J. Org. Chem., 2011, 5246-5249.

54. An oxide-centered trinuclear manganese(III) compound with a bulky phenol-pyrazolate ligand. M. Viciano-Chumillas, S. Tanase, O. Roubeau, S. J. Teat, L. J. de Jongh, J. Reedijk Eur. J. Inorg. Chem., 2010, 947-951.

53. Coordination versatility of pyrazole-based ligands towards high-nuclearity transition-metal and rare-earth clusters. M. Viciano-Chumillas, S. Tanase, L. J. de Jongh, J. Reedijk Eur. J. Inorg. Chem., 2010, 3403-3418.

52. High nuclearity manganese(III) compounds containing phenol-pyrazole ligands: the influence of the ligand on the core geometry. M. Viciano-Chumillas, G. de Ruiter, S. Tanase, J. M. M. Smits, R. de Gelder, I. Mutikainen, U. Turpeinen, L. J. de Jongh, J. Reedijk Dalton Trans., 2010, 39, 4991-4998.

51. Anion-induced assembly of hexacoordinate rare-earth(III) complexes. S. Tanase, S. Sottini, V. Marvaud, E. J. J. Groenen, L. M. Chamoreau Eur. J. Inorg. Chem., 2010, 3478-3483.

50. Hydrocarbon oxidation with H2O2, catalyzed by iron complexes with a polydentate pyridine-based ligand. S. Tanase, J. Reedijk, R. Hage, G. Rothenberg Top. Catal., 2010, 53, 1039-1044.

49. Manganese(III) compounds with phenol-pyrazole based-ligands: impact of the co-ligand and the carboxylate ligand on the trinuclear core [Mn3(m3-O)(phpzR)3(O2CR')n](1-n). M. Viciano-Chumillas, S. Tanase, I. Mutikainen, U. Turpeinen, L. J. de Jongh, J. Reedijk Dalton Trans., 2009, 7445-7453.

48. Copper(II) and lanthanoid(III) complexes of a new beta-diketonate ligand with an appended non-coordinating phenol group. S. Tanase, M. Viciano-Chumillas, J. M. M. Smits, R. de Gelder, J. Reedijk Polyhedron, 2009, 28, 457-460.

47. Cytotoxic activity and cellular processing in human ovarian carcinoma cell lines of a new platinum(II) compound containing a fluorescent substituted propylene diamine ligand. P. Marques-Gallego, H. den Dulk, J. Brouwer, S. Tanase, I. Mutikainen, U. Turpeinen, J. Reedijk Biochem. Pharmacol., 2009, 78, 365-373.

46. Combined Mossbauer spectral and Density Functional Theory determination of the magnetic easy-axis in two high-spin iron(II) 2-pyrazinecarboxylate complexes. G. J. Long, S. Tanase, F. Remacle, G. Periyasamy, F. Grandjean Inorg. Chem., 2009, 48, 8173-8179.

45. Mononuclear manganese(III) complexes as building blocks for the design of trinuclear manganese clusters: Study of the ligand influence on the magnetic properties of the [Mn3(m3-O)]7+ core. M. Viciano-Chumillas, S. Tanase, I. Mutikainen, U. Turpeinen, L. J. de Jongh, J. Reedijk Inorg. Chem., 2008, 47, 5919-5929.

44. Manganese(III) compounds of phenol-pyrazole-based ligands: Synthesis, crystal structure, magnetic, and thermal properties. M. Viciano-Chumillas, M. Gimenez-Marques, S. Tanase, M. Evangelisti, I. Mutikainen, U. Turpeinen, J. M. M. Smits, R. de Gelder, L. J. de Jongh, J. Reedijk J. Phys. Chem. C, 2008, 112, 20525-20534.

43. Extended networks generated from the interaction of rare-earth(III) ions and pyridine-2-carboxamide-based ligands. M. G. van der Horst, G. A. van Albada, R. M. Ion, I. Mutikainen, U. Turpeinen, S. Tanase, J. Reedijk Eur. J. Inorg. Chem., 2008, 2170-2176.

42. A bis(chlorido)-bridged linear-chain Cu(II) compound with 7-azaindole as an axial ligand; synthesis, structure, hydrogen bonding and magnetism. G. A. van Albada, S. Tanase, I. Mutikainen, U. Turpeinen, J. Reedijk Inorg. Chim. Acta, 2008, 361, 1463-1468.

41. Mechanistic implications of the active species involved in the oxidation of hydrocarbons by iron complexes of pyrazine-2-carboxylic acid. S. Tanase, P. Marques-Gallego, W. R. Browne, R. Hage, E. Bouwman, B. L. Feringa, J. Reedijk Dalton Trans., 2008, 2026-2033.

40. Crystal structure, magnetic and thermal properties of the one-dimensional complex Nd(pzam)3(H2O)Mo(CN)8.H2O. S. Tanase, M. Evangelisti, L. J. de Jongh, J. M. M. Smits, R. de Gelder Inorg. Chim. Acta, 2008, 361, 3548-3554.

39. Ferrimagnetic Heisenberg chains derived from [M(CN)8]3- (M = MoV, WV) building-blocks. S. Tanase, L. J. de Jongh, F. Prins, M. Evangelisti ChemPhysChem, 2008, 9, 1975-1978.

38. A Novel Ni4 complex exhibiting microsecond quantum tunneling of the magnetization. G. Aromi, E. Bouwman, E. Burzuri, C. Carbonera, J. Krzystek, F. Luis, C. Schlegel, J. van Slageren, S. Tanase, S. J. Teat Chem.-Eur. J., 2008, 14, 11158-11166.

37. Coordination versatility of 5(3)-(2-hydroxyphenyl)-3(5)-methylpyrazole: Synthesis, crystal structure and properties of CoIII, NiII and CuII complexes. M. Viciano-Chumillas, S. Tanase, G. Aromi, J. M. M. Smits, R. de Gelder, X. Solans, E. Bouwman, J. Reedijk Eur. J. Inorg. Chem., 2007, 2635-2640.

36. Synthesis, crystal structure and photophysical properties of europium(III) and terbium(III) complexes with pyridine-2,6-dicarboxamide. S. Tanase, P. M. Gallego, R. de Gelder, W. T. Fu Inorg. Chim. Acta, 2007, 360, 102-108.

35. Long-range magnetic ordering in a TbIII-MoV cyanido-bridged quasi-one-dimensional complex. F. Prins, E. Pasca, L. J. de Jongh, H. Kooijman, A. L. Spek, S. Tanase Angew. Chem.-Int. Edit., 2007, 46, 6081-6084.

34. Changes in magnetic properties from solid state to solution in a trinuclear linear copper(II) complex. I. A. Koval, H. Akhideno, S. Tanase, C. Belle, C. Duboc, E. Saint-Aman, P. Gamez, D. M. Tooke, A. L. Spek, J. L. Pierre, J. Reedijk New J. Chem., 2007, 31, 512-518.

33. Iron complexes of chiral phenol-oxazoline ligands: Structural studies and oxidation catalysis. M. D. Godbole, M. P. Puig, S. Tanase, H. Kooijman, A. L. Spek, E. Bouwman Inorg. Chim. Acta, 2007, 360, 1954-1960.

32. Synthesis, structure and magnetism of two new polymeric double dicyanamido-bridged Mn(II) compounds. G. A. van Albada, S. Tanase, A. Mohamadou, I. Mutikainen, U. Turpeinen, J. Reedijk Polyhedron, 2006, 25, 2236-2240.

31. Self-assembly of extended structures through non-coordination intermolecular forces: Synthesis, crystal structures, and properties of metal complexes with 5-methyl-2-pyrazinecarboxylate. S. Tanase, M. van Son, G. A. van Albada, R. de Gelder, E. Bouwman, J. Reedijk Polyhedron, 2006, 25, 2967-2975.

30. Chemistry and magnetism of cyanido-bridged d-f assemblies. S. Tanase, J. Reedijk Coord. Chem. Rev., 2006, 250, 2501-2510.

29. Three-dimensional LnIII-WIV complexes with cyanido and carboxylato bridges. S. Tanase, F. Prins, J. M. M. Smits, R. de Gelder Crystengcomm, 2006, 8, 863-865.

28. Versatility in the binding of 2-pyrazinecarboxylate with iron. Synthesis, structure and magnetic properties of iron(II) and iron(III) complexes. S. Tanase, P. M. Gallego, E. Bouwman, G. J. Long, L. Rebbouh, F. Grandjean, R. de Gelder, I. Mutikainen, U. Turpeinen, J. Reedijk Dalton Trans., 2006, 1675-1684.

27. Selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysts. S. Tanase, E. Bouwman Adv. Inorg. Chem., 2006, 58, 29-75.

26. Bis[bis(2-pyridylcarbonyl)aminato]iron(III) perchlorate acetonitrile disolvate. H. Kooijman, S. Tanase, E. Bouwman, J. Reedijk, A. L. Spek Acta Cryst. E, 2006, C62, m510-m512.

25. Low-spin iron(III) Schiff-base complexes with symmetric hexadentate ligands: Synthesis, crystal structure, spectroscopic and magnetic properties. R. Kannappan, S. Tanase, I. Mutikainen, U. Turpeinen, J. Reedijk Polyhedron, 2006, 25, 1646-1654.

24. A copper(II) chain compound with hydrogenphosphate bridges organized in a double-chain structure. Synthesis, structure and magnetic properties of [Cu(1,10-phenanthroline)(m-HPO4)(H2O)2]n. S. Youngme, P. Phuengphai, C. Pakawatchai, G. A. van Albada, S. Tanase, P. Mutikainen, U. Turpeinen, J. Reedijk Inorg. Chem. Commun., 2005, 8, 335-338.

23. Synthesis, crystal structure and magnetic properties of a polynuclear Cu(II) complex: catena-poly-aqua(di-2-pyridylamine)copper(II)(m-formato-O,O')nitrate. S. Youngme, P. Phuengphai, N. Chaichit, G. A. van Albada, S. Tanase, J. Reedijk Inorg. Chim. Acta, 2005, 358, 3267-3271.

22. Crystal structure, magnetic properties and spectroscopic characterization of a rare syn-anti acetato-bridged zig-zag chain copper(II) complex. S. Tanase, G. A. van Albada, R. de Gelder, E. Bouwman, J. Reedijk Polyhedron, 2005, 24, 979-983.

21. Ligand conformation enforces trigonal bipyramidal coordination geometry in a new dinuclear bis(pyrazolato)-bridged copper(II) complex: synthesis, crystal structure, and properties of Cu(Npy2pz)2(ClO4)2.2CH3CN. S. Tanase, I. A. Koval, E. Bouwman, R. de Gelder, J. Reedijk Inorg. Chem., 2005, 44, 7860-7865.

20. A new polymeric copper(II) complex containing pyrazine-2-carboxyamide (pzca): Synthesis and crystal structure of {Cu(pzca)(CH3CN)3(ClO4)2.H2O}n. S. Tanase, P. M. Gallego, E. Bouwman, R. de Gelder, J. Reedijk Inorg. Chem. Commun., 2005, 8, 680-683.

19. Control of the catalytic oxidations mediated by an oxo-bridged non-heme diiron complex: role of additives and reaction conditions. S. Tanase, C. Foltz, R. de Gelder, R. Hage, E. Bouwman, J. Reedijk J. Mol. Catal. A-Chem., 2005, 225, 161-167.

18. Bis(m-alkoxo)-bridged dinuclear iron(III) complexes of pyrazole-based ligands as models for iron-oxo proteins. S. Tanase, E. Bouwman, G. J. Long, A. M. Shahin, R. de Gelder, A. M. Mills, A. L. Spek, J. Reedijk Polyhedron, 2005, 24, 41-48.

17. New routes to manganese higher-nuclearity topologies: synthesis of the cluster Mn8(m4-O)4(phpz)8(thf)4. S. Tanase, G. Aromi, E. Bouwman, H. Kooijman, A. L. Spek, J. Reedijk Chem. Commun., 2005, 3147-3149.

16. m-Oxo-bis{chloro N-(2-methoxyethyl)-N,N-bis(pyridin-2-ylmethyl)amine-kappa(4)-N,N ',N '',O iron(III}bis(trifluoromethanesulfonate) acetonitrile disolvate. H. Kooijman, M. van Son, S. Tanase, E. Bouwman, J. Reedijk, A. L. Spek Acta Crystallogr. Sect. E.-Struct Rep. Online, 2005, 61, M1042-M1044.

15. Square-planar copper(II) halide complexes of tridentate ligands with p-p stacking interactions and alternating short and long Cu...Cu distances. R. Kannappan, S. Tanase, I. Mutikainen, U. Turpeinen, J. Reedijk Inorg. Chim. Acta, 2005, 358, 383-388.

14. A dinuclear Mn(II) chloro-bridged compound with a weak ferromagnetic Mn-Mn interaction - Synthesis, structure, EPR and magnetism of Mn(m-Cl)(2,2'-bis-imidazoline)2Cl2. G. A. van Albada, A. Mohamadou, W. L. Driessen, R. de Gelder, S. Tanase, J. Reedijk Polyhedron, 2004, 23, 2387-2391.

13. Synthesis and structural studies of two new base adducts of bis(2,4-pentanedionato)cobalt(II). S. Tanase, E. Bouwman, J. Reedijk, W. L. Driessen, M. Ferbinteanu, M. Huber, A. M. Mills, A. L. Spek Eur. J. Inorg. Chem., 2004, 1963-1969.

12. Role of additives in cobalt-mediated oxidative crosslinking of alkyd resins. S. Tanase, E. Bouwman, J. Reedijk Appl. Catal. A-Gen., 2004, 259, 101-107.

11. Acid-base self-assembly chemistry and hydrogen bonding interactions resulting in the formation of a ‘tetranuclear cluster’ containing four non-equivalent Fe(III) centers. S. Tanase, E. Bouwman, G. J. Long, A. M. Shahin, J. Reedijk, A. M. Mills, A. L. Spek Eur. J. Inorg. Chem., 2004, 4572-4578.

10. Separation of actinides and lanthanides: crystal and molecular structures of N,N '-bis(3,5-di-t-butylsalicylidene)-4,5-dimethyl-1,2-phenylenediamine and its uranium complex. R. Kannappan, S. Tanase, D. M. Tooke, A. L. Spek, I. Mutikainen, U. Turpeinen, J. Reedijk Polyhedron, 2004, 23, 2285-2291.

9. Extended structures based on hydrogen bonding and p-p interactions: synthesis and characterization of two zinc complexes: Zn(dap)Cl2 and Zn(dap)2Cl2. C. de Cires-Mejias, S. Tanase, J. Reedijk, F. Gonzalez-Vilchez, R. Vilaplana, A. M. Mills, H. Kooijman, A. L. Spek Inorg. Chim. Acta, 2004, 357, 1494-1498.

8. Synthesis, structure and magnetic properties of a linear-chain manganese(II) complex [Mn(m-Cl)2(mppma)]n, where mppma is N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine. J. Z. Wu, S. Tanase, E. Bouwman, J. Reedijk, A. M. Mills, A. L. Spek Inorg. Chim. Acta, 2003, 351, 278-282.

7. Substantial increase of the ordering temperature for {MnII/MoIII(CN)7}-based magnets as a function of the 3d ion site geometry: Example of two supramolecular materials with Tc=75 and 106 K. S. Tanase, F. Tuna, P. Guionneau, T. Maris, G. Rombaut, C. Mathoniere, M. Andruh, O. Kahn, J. P. Sutter Inorg. Chem., 2003, 42, 1625-1631.

6. New insights on the anti-skinning effect of methyl ethyl ketoxime in alkyd paints. S. Tanase, J. C. Hierso, E. Bouwman, J. Reedijk, J. ter Borg, J. H. Bieleman, A. Schut New J. Chem., 2003, 27, 854-859.

5. A new di-m-alkoxo-bridged dinuclear copper(II) complex of 1-(2-hydroxyethyl)-pyrazole. Synthesis, spectroscopic and magnetic properties and crystal structure. S. Tanase, E. Bouwman, W. L. Driessen, J. Reedijk, R. de Gelder Inorg. Chim. Acta, 2003, 355, 458-461.

4. A novel cyano-bridged pentanuclear complex: {Mn3(MAC)3(H2O)2}Fe(CN)6}2.6H2O.2CH3OH - synthesis, crystal structure and, magnetic properties (MAC=pentaaza macrocyclic ligand). S. Tanase, M. Andruh, N. Stanica, C. Mathoniere, G. Rombaut, S. Golhen, L. Ouahab Polyhedron, 2003, 22, 1315-1320.

3. Construction of 3d-4f heterometallic coordination polymers by simultaneous use of hexacyanometalate building-blocks and exo-bidentate ligands. S. Tanase, M. Andruh, A. Muller, M. Schmidtmann, C. Mathoniere, G. Rombaut Chem. Commun., 2001, 1084-1085.

2. Synthesis and characterization of a new molecular magnet, [Ni(ampy)2]3[Fe(CN)6]2.6H2O, and synthesis, crystal structure and magnetic properties of its mononuclear precursor, trans-Ni(ampy)2(NO3)2 (ampy=2-aminomethylpyridine). S. Tanase, M. Ferbinteanu, M. Andruh, C. Mathoniere, I. Strenger, G. Rombaut Polyhedron, 2000, 19, 1967-1973.

1. Synthesis, crystal structure and magnetic properties of the cyano-bridged heteropolynuclear complex {(Cu(dien))2Co(CN)6}nCu(dien)(H2O)Co(CN)6.5nH2O. M. Ferbinteanu, S. Tanase, M. Andruh, Y. Journaux, F. Cimpoesu, I. Strenger, E. Riviere Polyhedron, 1999, 18, 3019-3025.

 

 

The inorganic materials team develops efficient, selective, and sustainable synthetic methodologies for target-oriented preparation of hybrid inorganic-organic materials (MOFs). We use these materials in various applications:

Molecular separations

The separation and purification steps costs a staggering amount of energy worldwide. The technology (mainly distillation) is mature and low-risk, and therefore companies keep on using it. However, distillation is unpractical when the boiling points are close or when the liquid mixtures are composed of reactive components. One alternative for distillation is adsorptive separation using porous solids. The driving forces are kinetic, enthalpy and, most promising, entropic factors.

We develop synthetic strategies for making crystalline microporous materials and their corresponding composites membranes for removing the water from alcohol-water mixtures. This research is highly relevant for bio-fuels purification and air drying. We are also designing new materials for separating saturated, unsaturated and aromatic hydrocarbon mixtures. Using predictions from state-of-the-art molecular simulations (performed in the group of Dr. David Dubbeldam at the University of Amsterdam), we design and synthesise porous materials with tuneable pore geometries and network topologies. These materials are tested in separating C4 and C8 hydrocarbon mixtures under simulated industrial scenarios.

Molecular sensing

Sensor devices play a key role in industry and modern life, including process engineering and monitoring, medical technology, automotive and aerospace industry, and in safety and security technology. State-of-the-art sensing devices, using inorganic oxides or organic polymer materials, still lack advanced sensitivity and selectivity, therefore limiting key applications.

We aim at developing nanostructured lanthanide-based microporous materials which can be used as optically responsive sensors. The host-guest interactions within these materials allow the pre-concentration of analyte molecules within the pores, which is responsible for highly sensitive detection. We control the selective detection by tuning the functionality of the pore walls. This promotes preferred analyte binding, affording selective molecular detection.

Proton conductive materials

Proton exchange membranes fuel cells turn the chemical energy of fuel into electrical energy without fuel combustion. This is a promising technology for clean and efficient power generation. State-of-the-art cells use Nafion-type membranes. These, however, have two thorny limitations: First, they are prone to dehydration, losing their proton conductivity above 80 °C. Second, they are expensive, preventing large-scale commercial applications.

We design porous materials for low-temperature exchange membranes fuel cells and we carry out studies to understand the mechanisms of the proton conductivity. We further process these materials as composite membranes and study their performances in conditions relevant to real-life applications.

Catalysis in confined space

Asymmetric catalysis plays a key role in modern chemistry, especially in the field of pharmaceuticals. Homogenous catalysts are usually employed because of their excellent activities and selectivities. Using heterogenous catalysts has the main advantage of easy catalyst separation from the product stream. This would facilitate the implementation of continuous chemical processes.

We aim at developing synthetic strategies for designing basic chiral MOF materials, which can be used as heterogeneous catalysts in aminocatalytic alkylations. Such materials offer great catalytic efficiency and economy in contrast to the bulky heterogeneous catalysts that have catalytically active sites only at the solid surface. The intrinsic porous structure of MOFs imposes a special confinement with the catalytic reaction taking place in a chemically and sterically tunable environment.

BSc and MSc students wishing to carry out their research project in the inorganic materials team are welcome to discuss the opportunities with Dr. Stefania Grecea.

2017

  • Askes, S. H. C., Leeuwenburgh, V. C., Pomp, W., Arjmandi-Tash, H., Grecea, S., Schmidt, T., & Bonnet, S. (2017). Water-Dispersible Silica-Coated Upconverting Liposomes: Can a Thin Silica Layer Protect TTA-UC against Oxygen Quenching? ACS BIOMATERIALS SCIENCE ENGINEERING, 3(3), 322-334. DOI: 10.1021/acsbiomaterials.6b00678 
  • Gao, Y., Jing, P., Yan, N., Hilbers, M., Zhang, H., Rothenberg, G., & Grecea, S. (2017). Dual-mode humidity detection using a lanthanide-based metal-organic framework: towards multifunctional humidity sensors. Chemical Communications, 43(32). DOI: 10.1039/C7CC01122A 

2016

2015

2014

  • Dantas Ramos, A. L., Tanase, S., & Rothenberg, G. (2014). Redes metalorgânicas e suas aplicações em catálise. Química Nova, 37(1), 123-133. DOI: 10.1590/S0100-40422014000100021  [details] 
  • Strassberger, Z., Tanase, S., & Rothenberg, G. (2014). The pros and cons of lignin valorisation in an integrated biorefinery. RSC ADVANCES, 4(48), 25310-25318. DOI: 10.1039/c4ra04747h  [details] 
  • Plessius, R., Kromhout, R., Dantas Ramos, A. L., Ferbinteanu, M., Mittelmeijer-Hazeleger, M. C., Krishna, R., ... Tanase, S. (2014). Highly Selective Water Adsorption in a Lanthanum Metal-Organic Framework. Chemistry - A European Journal, 20(26), 7922-7925. DOI: 10.1002/chem.201403241  [details] 

2013

2012

  • Grecea, M. L., Dimian, A. C., Tanase, S., Subbiah, V., & Rothenberg, G. (2012). Sulfated zirconia as a robust superacid catalyst for multiproduct fatty acid esterification. Catalysis Science & Technology, 2(7), 1500-1506. DOI: 10.1039/c2cy00432a  [details] 
  • Ferbinteanu, M., Cimpoesu, F., Gîrtu, M. A., Enachescu, C., & Tanase, S. (2012). Structure and magnetism in Fe-Gd based dinuclear and chain systems: the interplay of weak exchange coupling and zero field splitting effects. Inorganic Chemistry, 51(1), 40-50. DOI: 10.1021/ic1023289  [details] 
  • Pasca, E., Roscilde, T., Evangelisti, M., Burzurí, E., Luis, F., de Jongh, L. J., & Tanase, S. (2012). Realization of the one-dimensional anisotropic XY model in a Tb(III)-W(V) chain compound. Physical Review B, 85(18), 184434. DOI: 10.1103/PhysRevB.85.184434  [details] 
  • Viciano-Chumillas, M., Giménez-Marqués, M., Tanase, S., Mutikainen, I., Turpeinen, U., Smits, J. M. M., ... Reedijk, J. (2012). Mononuclear and dinuclear manganese compounds stabilized by supramolecular interactions. Dalton Transactions, 41(34), 10249-10257. DOI: 10.1039/c2dt31060k  [details] 
  • Viciano-Chumillas, M., Tanase, S., Mutikainen, I., Turpeinen, U., de Jongh, L. J., & Reedijk, J. (2012). A dinuclear manganese(III) and a rare pentanuclear manganese(III) compound with a phenol-pyrazole ligand. Polyhedron, 38(1), 178-184. DOI: 10.1016/j.poly.2012.03.001  [details] 

2011

  • Strassberger, Z., Tanase, S., & Rothenberg, G. (2011). Reductive dealkylation of anisole and phenetole: towards practical lignin conversion. European Journal of Organic Chemistry, 2011(27), 5246-5249. DOI: 10.1002/ejoc.201101015  [details] 
  • Tanase, S., Evangelisti, M., & de Jongh, L. J. (2011). Short-range correlations in d-f cyanido-bridged assemblies with XY and XY-Heisenberg anisotropy. Dalton Transactions, 40(33), 8407-8413. DOI: 10.1039/c1dt10310e  [details] 
  • Tanase, S., Ferbinteanu, M., & Cimpoesu, F. (2011). Rationalization of the lanthanide-ion-driven magnetic properties in a series of 4f-5d cyano-bridged chains. Inorganic Chemistry, 50(19), 9678-9687. DOI: 10.1021/ic201427w  [details] 
  • Tanase, S., Mittelmeijer-Hazeleger, M. C., Rothenberg, G., Mathonière, C., Jubera, V., Smits, J. M. M., & de Gelder, R. (2011). A facile building-block synthesis of multifunctional lanthanide MOFs. Journal of Materials Chemistry, 21(39), 15544-15551. DOI: 10.1039/c1jm12789f  [details] 

2010

  • Tanase, S., Reedijk, J., Hage, R., & Rothenberg, G. (2010). Hydrocarbon oxidation with H2O2, catalyzed by iron complexes with a polydentate pyridine-based ligand. Topics in Catalysis, 53(15-18), 1039-1044. DOI: 10.1007/s11244-010-9528-2  [details] 
This list of publications is extracted from the UvA-Current Research Information System. Questions? Ask the library  or the Pure staff  of your faculty / institute. Log in to Pure  to edit your publications.
  • Geen nevenwerkzaamheden

contactgegevens bewerken bewerk tabbladen